Ketone synthesis by intramolecular acylation of organorhodium(I) with Ester

Tomoya Miura; Taisuke Sasaki; Hiroki Nakazawa; Masahiro Murakami

doi:10.1021/ja043123i

Ketone synthesis by intramolecular acylation of organorhodium(I) with Ester

Tomoya Miura, Taisuke Sasaki, Hiroki Nakazawa, Masahiro Murakami

Research output: Contribution to journal › Article › peer-review

53 Citations (Scopus)

Abstract

New cyclization reactions forming cyclic ketones were developed wherein an intermediate organorhodium(I) species underwent intramolecular acylation with an ester group. A 2-norbornanone skeleton is constructed in a single operation through successive multiple carbon-carbon bond formation. The reactions ended up with generation of an alkoxyrhodium(I) species to promote the next catalytic cycle.

Original language	English
Pages (from-to)	1390-1391
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	127
Issue number	5
DOIs	https://doi.org/10.1021/ja043123i
Publication status	Published - Feb 9 2005
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

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10.1021/ja043123i

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abstract = "New cyclization reactions forming cyclic ketones were developed wherein an intermediate organorhodium(I) species underwent intramolecular acylation with an ester group. A 2-norbornanone skeleton is constructed in a single operation through successive multiple carbon-carbon bond formation. The reactions ended up with generation of an alkoxyrhodium(I) species to promote the next catalytic cycle.",

author = "Tomoya Miura and Taisuke Sasaki and Hiroki Nakazawa and Masahiro Murakami",

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AU - Miura, Tomoya

AU - Sasaki, Taisuke

AU - Nakazawa, Hiroki

AU - Murakami, Masahiro

PY - 2005/2/9

Y1 - 2005/2/9

N2 - New cyclization reactions forming cyclic ketones were developed wherein an intermediate organorhodium(I) species underwent intramolecular acylation with an ester group. A 2-norbornanone skeleton is constructed in a single operation through successive multiple carbon-carbon bond formation. The reactions ended up with generation of an alkoxyrhodium(I) species to promote the next catalytic cycle.

AB - New cyclization reactions forming cyclic ketones were developed wherein an intermediate organorhodium(I) species underwent intramolecular acylation with an ester group. A 2-norbornanone skeleton is constructed in a single operation through successive multiple carbon-carbon bond formation. The reactions ended up with generation of an alkoxyrhodium(I) species to promote the next catalytic cycle.

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Ketone synthesis by intramolecular acylation of organorhodium(I) with Ester

Abstract

ASJC Scopus subject areas

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