Ligand exchange reaction of (Me4N) 4 [Cd10S4 (SPh) 16] with diphenyl diselenide

Tomoyuki Tajima; Shoko Yamamoto; Yuta Sakamoto; Shoji Takagi; Toshitaka Nakaya; Yutaka Takaguchi; Asako Igashira-Kamiyama; Nobuto Yoshinari; Takumi Konno

doi:10.1246/bcsj.20160395

Ligand exchange reaction of (Me₄N) ₄ [Cd₁₀S₄ (SPh) ₁₆] with diphenyl diselenide

Tomoyuki Tajima, Shoko Yamamoto, Yuta Sakamoto, Shoji Takagi, Toshitaka Nakaya, Yutaka Takaguchi, Asako Igashira-Kamiyama, Nobuto Yoshinari, Takumi Konno

Research output: Contribution to journal › Article › peer-review

Abstract

The reaction of (Me4N)4[Cd10S4(SPh)16] (1) with diphenyl diselenide (2) in propionitrile afforded a molecular cluster, (Me4N)4[Cd10S4(SePh)16] (3), the structure of which was determined by X-ray crystallography. Ligand exchange proceeded in a heterogeneous reaction system, and the use of a less polar solvent appeared to be crucial for the synthesis of 3 to prevent degradation of the Cd10S4Se16 cluster core.

Original language	English
Pages (from-to)	384-386
Number of pages	3
Journal	Bulletin of the Chemical Society of Japan
Volume	90
Issue number	4
DOIs	https://doi.org/10.1246/bcsj.20160395
Publication status	Published - 2017

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Chemistry(all)

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title = "Ligand exchange reaction of (Me4N) 4 [Cd10S4 (SPh) 16] with diphenyl diselenide",

abstract = "The reaction of (Me4N)4[Cd10S4(SPh)16] (1) with diphenyl diselenide (2) in propionitrile afforded a molecular cluster, (Me4N)4[Cd10S4(SePh)16] (3), the structure of which was determined by X-ray crystallography. Ligand exchange proceeded in a heterogeneous reaction system, and the use of a less polar solvent appeared to be crucial for the synthesis of 3 to prevent degradation of the Cd10S4Se16 cluster core.",

author = "Tomoyuki Tajima and Shoko Yamamoto and Yuta Sakamoto and Shoji Takagi and Toshitaka Nakaya and Yutaka Takaguchi and Asako Igashira-Kamiyama and Nobuto Yoshinari and Takumi Konno",

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doi = "10.1246/bcsj.20160395",

language = "English",

volume = "90",

pages = "384--386",

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T1 - Ligand exchange reaction of (Me4N) 4 [Cd10S4 (SPh) 16] with diphenyl diselenide

AU - Tajima, Tomoyuki

AU - Yamamoto, Shoko

AU - Sakamoto, Yuta

AU - Takagi, Shoji

AU - Nakaya, Toshitaka

AU - Takaguchi, Yutaka

AU - Igashira-Kamiyama, Asako

AU - Yoshinari, Nobuto

AU - Konno, Takumi

PY - 2017

Y1 - 2017

N2 - The reaction of (Me4N)4[Cd10S4(SPh)16] (1) with diphenyl diselenide (2) in propionitrile afforded a molecular cluster, (Me4N)4[Cd10S4(SePh)16] (3), the structure of which was determined by X-ray crystallography. Ligand exchange proceeded in a heterogeneous reaction system, and the use of a less polar solvent appeared to be crucial for the synthesis of 3 to prevent degradation of the Cd10S4Se16 cluster core.

AB - The reaction of (Me4N)4[Cd10S4(SPh)16] (1) with diphenyl diselenide (2) in propionitrile afforded a molecular cluster, (Me4N)4[Cd10S4(SePh)16] (3), the structure of which was determined by X-ray crystallography. Ligand exchange proceeded in a heterogeneous reaction system, and the use of a less polar solvent appeared to be crucial for the synthesis of 3 to prevent degradation of the Cd10S4Se16 cluster core.

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ER -

Ligand exchange reaction of (Me₄N) ₄ [Cd₁₀S₄ (SPh) ₁₆] with diphenyl diselenide

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