Local structures around the Rb+ ion in K2RbC60 and KRB2C60 studied by Rb K-edge EXAFS

Y. Kubozono; T. Urakawa; Y. Yoshida; H. Maeda; H. Ishida; Y. Furukawa; K. Yamada; S. Kashino

doi:10.1016/0009-2614(96)00324-7

Local structures around the Rb⁺ ion in K₂RbC₆₀ and KRB₂C₆₀ studied by Rb K-edge EXAFS

Y. Kubozono, T. Urakawa, Y. Yoshida, H. Maeda, H. Ishida, Y. Furukawa, K. Yamada, S. Kashino

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Abstract

Rb K-edge EXAFS has been studied for K₂RbC₆₀ at 21 and 39 K and for KRb₂C₆₀ at 10 and 27 K. It is shown that the Rb⁺ ions in K₂RbC₆₀ occupy the center of the octahedral site, contrary to a previous report based on Rb K-edge EXAFS at room temperature that the Rb⁺ ions are off-centered. It is also found that the Rb⁺ ions in KRb₂C₆₀ occupy the octahedral and two tetrahedral sites.

Original language	English
Pages (from-to)	19-24
Number of pages	6
Journal	Chemical Physics Letters
Volume	255
Issue number	1-3
DOIs	https://doi.org/10.1016/0009-2614(96)00324-7
Publication status	Published - Jun 7 1996

ASJC Scopus subject areas

Physics and Astronomy(all)
Physical and Theoretical Chemistry

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title = "Local structures around the Rb+ ion in K2RbC60 and KRB2C60 studied by Rb K-edge EXAFS",

abstract = "Rb K-edge EXAFS has been studied for K2RbC60 at 21 and 39 K and for KRb2C60 at 10 and 27 K. It is shown that the Rb+ ions in K2RbC60 occupy the center of the octahedral site, contrary to a previous report based on Rb K-edge EXAFS at room temperature that the Rb+ ions are off-centered. It is also found that the Rb+ ions in KRb2C60 occupy the octahedral and two tetrahedral sites.",

author = "Y. Kubozono and T. Urakawa and Y. Yoshida and H. Maeda and H. Ishida and Y. Furukawa and K. Yamada and S. Kashino",

year = "1996",

month = jun,

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doi = "10.1016/0009-2614(96)00324-7",

language = "English",

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T1 - Local structures around the Rb+ ion in K2RbC60 and KRB2C60 studied by Rb K-edge EXAFS

AU - Kubozono, Y.

AU - Urakawa, T.

AU - Yoshida, Y.

AU - Maeda, H.

AU - Ishida, H.

AU - Furukawa, Y.

AU - Yamada, K.

AU - Kashino, S.

PY - 1996/6/7

Y1 - 1996/6/7

N2 - Rb K-edge EXAFS has been studied for K2RbC60 at 21 and 39 K and for KRb2C60 at 10 and 27 K. It is shown that the Rb+ ions in K2RbC60 occupy the center of the octahedral site, contrary to a previous report based on Rb K-edge EXAFS at room temperature that the Rb+ ions are off-centered. It is also found that the Rb+ ions in KRb2C60 occupy the octahedral and two tetrahedral sites.

AB - Rb K-edge EXAFS has been studied for K2RbC60 at 21 and 39 K and for KRb2C60 at 10 and 27 K. It is shown that the Rb+ ions in K2RbC60 occupy the center of the octahedral site, contrary to a previous report based on Rb K-edge EXAFS at room temperature that the Rb+ ions are off-centered. It is also found that the Rb+ ions in KRb2C60 occupy the octahedral and two tetrahedral sites.

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Local structures around the Rb⁺ ion in K₂RbC₆₀ and KRB₂C₆₀ studied by Rb K-edge EXAFS

Abstract

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