Abstract
We propose that shear rate γ̇ (Z) within the interface significantly increases and conformation of molecular chains will be elongated. When γ̇ (Z) becomes larger, the elongation of chains will overcome the entropic relaxation, that results in formation of the "oriented melt". Universal crystallization mechanism under shear flow is proposed that the growth rate of spherulite or shish is accelerated near the surface, that is due to formation of the oriented melt.
Original language | English |
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Pages | 626 |
Number of pages | 1 |
Publication status | Published - 2005 |
Externally published | Yes |
Event | 54th SPSJ Annual Meeting 2005 - Yokohama, Japan Duration: May 25 2005 → May 27 2005 |
Other
Other | 54th SPSJ Annual Meeting 2005 |
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Country/Territory | Japan |
City | Yokohama |
Period | 5/25/05 → 5/27/05 |
Keywords
- Crystallization/
- Isotropic melt
- Oriented melt
- Shear flow
- Spherulite
ASJC Scopus subject areas
- Engineering(all)