TY - JOUR
T1 - Metastable sorption state of a metal-organic porous material determined by in situ synchrotron powder diffraction
AU - Kubota, Yoshiki
AU - Takata, Masaki
AU - Matsuda, Ryotaro
AU - Kitaura, Ryo
AU - Kitagawa, Susumu
AU - Kobayashi, Tatsuo C.
PY - 2006/7/24
Y1 - 2006/7/24
N2 - (Figure Presented) Guest-responsive framework: Gas adsorption into a metal-organic porous material was studies in situ. Structure analysis of empty phase I, intermediate phase M as a metastable state of gas adsorption, and saturated phase S showed rearrangement of guest molecules and framework transformation in response to guest size, shape, and amount. The picture shows these changes for the superimposed phases M and S.
AB - (Figure Presented) Guest-responsive framework: Gas adsorption into a metal-organic porous material was studies in situ. Structure analysis of empty phase I, intermediate phase M as a metastable state of gas adsorption, and saturated phase S showed rearrangement of guest molecules and framework transformation in response to guest size, shape, and amount. The picture shows these changes for the superimposed phases M and S.
KW - Adsorption
KW - Metal-organic frameworks
KW - Microporous materials
KW - Structure elucidation
KW - X-ray diffraction
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U2 - 10.1002/anie.200600976
DO - 10.1002/anie.200600976
M3 - Article
C2 - 16807951
AN - SCOPUS:33746771112
SN - 1433-7851
VL - 45
SP - 4932
EP - 4936
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
IS - 30
ER -