Molecular structure and electronic state of the dibenzo[a,e]pentalene anion radical

Masaichi Saito; Yoko Hashimoto; Tomoyuki Tajima; Kazuya Ishimura; Shigeru Nagase; Mao Minoura

doi:10.1002/asia.201100711

Molecular structure and electronic state of the dibenzo[a,e]pentalene anion radical

Masaichi Saito, Yoko Hashimoto, Tomoyuki Tajima, Kazuya Ishimura, Shigeru Nagase, Mao Minoura

Research output: Contribution to journal › Article › peer-review

21 Citations (Scopus)

Abstract

Undergoing a radical change! The reduction of dibenzo[a,e]pentalene by KC ₈ afforded the corresponding anion radical, the structure of which was characterized for the first time by X-ray diffraction analysis. The electronic state of the anion radical is discussed with the aid of theoretical calculations.

Original language	English
Pages (from-to)	480-483
Number of pages	4
Journal	Chemistry - An Asian Journal
Volume	7
Issue number	3
DOIs	https://doi.org/10.1002/asia.201100711
Publication status	Published - Mar 5 2012
Externally published	Yes

Keywords

annulenes
electronic structure
lithium
radical ions
reduction

ASJC Scopus subject areas

Biochemistry
Organic Chemistry

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10.1002/asia.201100711

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abstract = "Undergoing a radical change! The reduction of dibenzo[a,e]pentalene by KC 8 afforded the corresponding anion radical, the structure of which was characterized for the first time by X-ray diffraction analysis. The electronic state of the anion radical is discussed with the aid of theoretical calculations.",

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AU - Saito, Masaichi

AU - Hashimoto, Yoko

AU - Tajima, Tomoyuki

AU - Ishimura, Kazuya

AU - Nagase, Shigeru

AU - Minoura, Mao

PY - 2012/3/5

Y1 - 2012/3/5

N2 - Undergoing a radical change! The reduction of dibenzo[a,e]pentalene by KC 8 afforded the corresponding anion radical, the structure of which was characterized for the first time by X-ray diffraction analysis. The electronic state of the anion radical is discussed with the aid of theoretical calculations.

AB - Undergoing a radical change! The reduction of dibenzo[a,e]pentalene by KC 8 afforded the corresponding anion radical, the structure of which was characterized for the first time by X-ray diffraction analysis. The electronic state of the anion radical is discussed with the aid of theoretical calculations.

KW - annulenes

KW - electronic structure

KW - lithium

KW - radical ions

KW - reduction

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Molecular structure and electronic state of the dibenzo[a,e]pentalene anion radical

Abstract

Keywords

ASJC Scopus subject areas

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