Morpholinium hydrogen chloranilate methanol monosolvate

Kazuma Gotoh; Yuki Tahara; Hiroyuki Ishida

doi:10.1107/S1600536811047891

Morpholinium hydrogen chloranilate methanol monosolvate

Kazuma Gotoh, Yuki Tahara, Hiroyuki Ishida

School of Science

Research output: Contribution to journal › Article › peer-review

Abstract

In the crystal structure of the title compound, C₄H ₁₀NO⁺·C₆HCl₂O₄ ^-·CH₄O, the components are held together by bifurcated O-H⋯(O,O), O-H⋯(O,Cl) and N-H⋯(O,O) hydrogen bonds into a centrosymmetric 2+2+2 aggregate. The aggregates are further connected by another bifurcated N-H⋯(O, O) hydrogen bond, forming a doubletape structure along the b axis. A weak C-H⋯O interaction is observed between the tapes..

Original language	English
Pages (from-to)	o3335
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	67
Issue number	12
DOIs	https://doi.org/10.1107/S1600536811047891
Publication status	Published - Dec 2011

Keywords

R factor = 0.027
T = 170 K
data-to-parameter ratio = 19.9
mean σ(C-C) = 0.002 Å
single-crystal X-ray study
wR factor = 0.077

ASJC Scopus subject areas

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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title = "Morpholinium hydrogen chloranilate methanol monosolvate",

abstract = "In the crystal structure of the title compound, C4H 10NO+·C6HCl2O4 -·CH4O, the components are held together by bifurcated O-H⋯(O,O), O-H⋯(O,Cl) and N-H⋯(O,O) hydrogen bonds into a centrosymmetric 2+2+2 aggregate. The aggregates are further connected by another bifurcated N-H⋯(O, O) hydrogen bond, forming a doubletape structure along the b axis. A weak C-H⋯O interaction is observed between the tapes..",

keywords = "R factor = 0.027, T = 170 K, data-to-parameter ratio = 19.9, mean σ(C-C) = 0.002 {\AA}, single-crystal X-ray study, wR factor = 0.077",

author = "Kazuma Gotoh and Yuki Tahara and Hiroyuki Ishida",

year = "2011",

month = dec,

doi = "10.1107/S1600536811047891",

language = "English",

volume = "67",

pages = "o3335",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "12",

}

TY - JOUR

T1 - Morpholinium hydrogen chloranilate methanol monosolvate

AU - Gotoh, Kazuma

AU - Tahara, Yuki

AU - Ishida, Hiroyuki

PY - 2011/12

Y1 - 2011/12

N2 - In the crystal structure of the title compound, C4H 10NO+·C6HCl2O4 -·CH4O, the components are held together by bifurcated O-H⋯(O,O), O-H⋯(O,Cl) and N-H⋯(O,O) hydrogen bonds into a centrosymmetric 2+2+2 aggregate. The aggregates are further connected by another bifurcated N-H⋯(O, O) hydrogen bond, forming a doubletape structure along the b axis. A weak C-H⋯O interaction is observed between the tapes..

AB - In the crystal structure of the title compound, C4H 10NO+·C6HCl2O4 -·CH4O, the components are held together by bifurcated O-H⋯(O,O), O-H⋯(O,Cl) and N-H⋯(O,O) hydrogen bonds into a centrosymmetric 2+2+2 aggregate. The aggregates are further connected by another bifurcated N-H⋯(O, O) hydrogen bond, forming a doubletape structure along the b axis. A weak C-H⋯O interaction is observed between the tapes..

KW - R factor = 0.027

KW - T = 170 K

KW - data-to-parameter ratio = 19.9

KW - mean σ(C-C) = 0.002 Å

KW - single-crystal X-ray study

KW - wR factor = 0.077

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U2 - 10.1107/S1600536811047891

DO - 10.1107/S1600536811047891

M3 - Article

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AN - SCOPUS:83155161714

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VL - 67

SP - o3335

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 12

ER -

Morpholinium hydrogen chloranilate methanol monosolvate

Abstract

Keywords

ASJC Scopus subject areas

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