Abstract
A new family of superconductors containing carbonate group has been reviewed. Especially, we emphasize the three new oxycarbonate compounds recently found in our laboratory. 1. Sr2CuO2(CO3)1-x(BO3)x (Tc≈35K) have been synthesized under an ambient pressure. This idea suggests the new method for carrier doping on layered copper oxycarbonate system. 2. Can(Ca,Sr)2Cun+1(CO3)Oy (n=1, 2, 3) have been synthesized under a high pressure(Tc 108K). The superconductivity could be achieved by substituting (BO3)3- for a part of (CO3)2-. 3. A new Hg-system HgBa2Sr2Cu2(CO3)O6+δ has been synthesized. Tc obtained from the magnetic susceptibility is about 66K.
Original language | English |
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Pages (from-to) | 84-88 |
Number of pages | 5 |
Journal | Denshi Gijutsu Sogo Kenkyusho Iho/Bulletin of the Electrotechnical Laboratory |
Volume | 58 |
Issue number | 6 |
Publication status | Published - Dec 1 1994 |
Externally published | Yes |
Event | Proceedings of ETL Workshop on High Temperature Superconductors - Tsukuba, Jpn Duration: Dec 6 1993 → Dec 8 1993 |
ASJC Scopus subject areas
- Condensed Matter Physics
- Electrical and Electronic Engineering