Nickel-catalyzed reductive defunctionalization of esters in the absence of an external reductant: Activation of C-O bonds

Yasuaki Iyori; Kenjiro Takahashi; Ken Yamazaki; Yusuke Ano; Naoto Chatani

doi:10.1039/c9cc07710c

Nickel-catalyzed reductive defunctionalization of esters in the absence of an external reductant: Activation of C-O bonds

Yasuaki Iyori, Kenjiro Takahashi, Ken Yamazaki, Yusuke Ano, Naoto Chatani

Research output: Contribution to journal › Article › peer-review

14 Citations (Scopus)

Abstract

The nickel-catalyzed reductive cleavage of esters in the absence of an external reductant, which involves the cleavage of an inert acyl C-O bond in O-Alkyl esters is reported. Various groups, such as N-containing heterocycles, esters, amides, and even arene rings can function as a directing group.

Original language	English
Pages (from-to)	13610-13613
Number of pages	4
Journal	Chemical Communications
Volume	55
Issue number	90
DOIs	https://doi.org/10.1039/c9cc07710c
Publication status	Published - 2019
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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abstract = "The nickel-catalyzed reductive cleavage of esters in the absence of an external reductant, which involves the cleavage of an inert acyl C-O bond in O-Alkyl esters is reported. Various groups, such as N-containing heterocycles, esters, amides, and even arene rings can function as a directing group.",

author = "Yasuaki Iyori and Kenjiro Takahashi and Ken Yamazaki and Yusuke Ano and Naoto Chatani",

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T1 - Nickel-catalyzed reductive defunctionalization of esters in the absence of an external reductant

T2 - Activation of C-O bonds

AU - Iyori, Yasuaki

AU - Takahashi, Kenjiro

AU - Yamazaki, Ken

AU - Ano, Yusuke

AU - Chatani, Naoto

N1 - Publisher Copyright: © The Royal Society of Chemistry.

PY - 2019

Y1 - 2019

N2 - The nickel-catalyzed reductive cleavage of esters in the absence of an external reductant, which involves the cleavage of an inert acyl C-O bond in O-Alkyl esters is reported. Various groups, such as N-containing heterocycles, esters, amides, and even arene rings can function as a directing group.

AB - The nickel-catalyzed reductive cleavage of esters in the absence of an external reductant, which involves the cleavage of an inert acyl C-O bond in O-Alkyl esters is reported. Various groups, such as N-containing heterocycles, esters, amides, and even arene rings can function as a directing group.

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Nickel-catalyzed reductive defunctionalization of esters in the absence of an external reductant: Activation of C-O bonds

Abstract

ASJC Scopus subject areas

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