N,N-diarylammonium pyrosulfate as a highly effective reverse micelle-type catalyst for hydrolysis of esters

Yoshiki Koshikari; Akira Sakakura; Kazuaki Ishihara

doi:10.1021/ol301290c

N,N-diarylammonium pyrosulfate as a highly effective reverse micelle-type catalyst for hydrolysis of esters

Yoshiki Koshikari, Akira Sakakura, Kazuaki Ishihara

Research output: Contribution to journal › Article › peer-review

22 Citations (Scopus)

Abstract

Reverse micelle-type N,N-diarylammonium pyrosulfate (3-5 mol %) efficiently catalyzes the hydrolysis of esters (up to 100 mmol scale) under organic solvent-free conditions. The present method is successfully applied to the hydrolysis of various esters without the decomposition of the base-sensitive moieties and without any loss of optical purity for α-heterosubstituted carboxylic acids.

Original language	English
Pages (from-to)	3194-3197
Number of pages	4
Journal	Organic Letters
Volume	14
Issue number	12
DOIs	https://doi.org/10.1021/ol301290c
Publication status	Published - Jun 15 2012
Externally published	Yes

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

Access to Document

10.1021/ol301290c

Cite this

@article{9e7a5bada14645398e3fa33389896add,

title = "N,N-diarylammonium pyrosulfate as a highly effective reverse micelle-type catalyst for hydrolysis of esters",

abstract = "Reverse micelle-type N,N-diarylammonium pyrosulfate (3-5 mol %) efficiently catalyzes the hydrolysis of esters (up to 100 mmol scale) under organic solvent-free conditions. The present method is successfully applied to the hydrolysis of various esters without the decomposition of the base-sensitive moieties and without any loss of optical purity for α-heterosubstituted carboxylic acids.",

author = "Yoshiki Koshikari and Akira Sakakura and Kazuaki Ishihara",

year = "2012",

month = jun,

day = "15",

doi = "10.1021/ol301290c",

language = "English",

volume = "14",

pages = "3194--3197",

journal = "Organic Letters",

issn = "1523-7060",

publisher = "American Chemical Society",

number = "12",

}

TY - JOUR

T1 - N,N-diarylammonium pyrosulfate as a highly effective reverse micelle-type catalyst for hydrolysis of esters

AU - Koshikari, Yoshiki

AU - Sakakura, Akira

AU - Ishihara, Kazuaki

PY - 2012/6/15

Y1 - 2012/6/15

N2 - Reverse micelle-type N,N-diarylammonium pyrosulfate (3-5 mol %) efficiently catalyzes the hydrolysis of esters (up to 100 mmol scale) under organic solvent-free conditions. The present method is successfully applied to the hydrolysis of various esters without the decomposition of the base-sensitive moieties and without any loss of optical purity for α-heterosubstituted carboxylic acids.

AB - Reverse micelle-type N,N-diarylammonium pyrosulfate (3-5 mol %) efficiently catalyzes the hydrolysis of esters (up to 100 mmol scale) under organic solvent-free conditions. The present method is successfully applied to the hydrolysis of various esters without the decomposition of the base-sensitive moieties and without any loss of optical purity for α-heterosubstituted carboxylic acids.

UR - http://www.scopus.com/inward/record.url?scp=84862512263&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84862512263&partnerID=8YFLogxK

U2 - 10.1021/ol301290c

DO - 10.1021/ol301290c

M3 - Article

C2 - 22646708

AN - SCOPUS:84862512263

SN - 1523-7060

VL - 14

SP - 3194

EP - 3197

JO - Organic Letters

JF - Organic Letters

IS - 12

ER -

N,N-diarylammonium pyrosulfate as a highly effective reverse micelle-type catalyst for hydrolysis of esters

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this