Non-sonogashira-type palladium-catalyzed coupling reactions of terminal alkynes assisted by silver(I) oxide or tetrabutylammonium fluoride

Atsunori Mori; Jun Kawashima; Tomohiro Shimada; Masahiro Suguro; Kazunori Hirabayashi; Yasushi Nishihara

doi:10.1021/ol0061586

Non-sonogashira-type palladium-catalyzed coupling reactions of terminal alkynes assisted by silver(I) oxide or tetrabutylammonium fluoride

Atsunori Mori, Jun Kawashima, Tomohiro Shimada, Masahiro Suguro, Kazunori Hirabayashi, Yasushi Nishihara

Research output: Contribution to journal › Article › peer-review

109 Citations (Scopus)

Abstract

Palladium-catalyzed reaction of aryl and alkenyl halides with terminal alkynes in the presence of silver(I) oxide as an activator furnishes various arylated or alkenylated alkynes in good to excellent yields. The similar coupling reaction is also found to proceed using tetrabutylammonium fluoride (TBAF) or tetrabutylammonium hydroxide (TBAOH) as an activator.

Original language	English
Pages (from-to)	2935-2937
Number of pages	3
Journal	Organic Letters
Volume	2
Issue number	19
DOIs	https://doi.org/10.1021/ol0061586
Publication status	Published - Sept 21 2000
Externally published	Yes

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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10.1021/ol0061586

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abstract = "Palladium-catalyzed reaction of aryl and alkenyl halides with terminal alkynes in the presence of silver(I) oxide as an activator furnishes various arylated or alkenylated alkynes in good to excellent yields. The similar coupling reaction is also found to proceed using tetrabutylammonium fluoride (TBAF) or tetrabutylammonium hydroxide (TBAOH) as an activator.",

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T1 - Non-sonogashira-type palladium-catalyzed coupling reactions of terminal alkynes assisted by silver(I) oxide or tetrabutylammonium fluoride

AU - Mori, Atsunori

AU - Kawashima, Jun

AU - Shimada, Tomohiro

AU - Suguro, Masahiro

AU - Hirabayashi, Kazunori

AU - Nishihara, Yasushi

PY - 2000/9/21

Y1 - 2000/9/21

N2 - Palladium-catalyzed reaction of aryl and alkenyl halides with terminal alkynes in the presence of silver(I) oxide as an activator furnishes various arylated or alkenylated alkynes in good to excellent yields. The similar coupling reaction is also found to proceed using tetrabutylammonium fluoride (TBAF) or tetrabutylammonium hydroxide (TBAOH) as an activator.

AB - Palladium-catalyzed reaction of aryl and alkenyl halides with terminal alkynes in the presence of silver(I) oxide as an activator furnishes various arylated or alkenylated alkynes in good to excellent yields. The similar coupling reaction is also found to proceed using tetrabutylammonium fluoride (TBAF) or tetrabutylammonium hydroxide (TBAOH) as an activator.

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Non-sonogashira-type palladium-catalyzed coupling reactions of terminal alkynes assisted by silver(I) oxide or tetrabutylammonium fluoride

Abstract

ASJC Scopus subject areas

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