Novel configurational structures of sodium tetrakis(3-heptafluorobutylryl- (+)-camphorato) Ln(III) complexes with a trapped Na + by Na +⋯FC interactions in the solid state and in solution

Dai Shirotani; Takayoshi Suzuki; Sumio Kaizaki

doi:10.1021/ic0606633

Novel configurational structures of sodium tetrakis(3-heptafluorobutylryl- (+)-camphorato) Ln(III) complexes with a trapped Na ⁺ by Na ⁺⋯FC interactions in the solid state and in solution

Dai Shirotani, Takayoshi Suzuki, Sumio Kaizaki

Research output: Contribution to journal › Article › peer-review

46 Citations (Scopus)

Abstract

For newly prepared sodium tetrakis(3-heplafluorobutylryl-(+)-camphorato) Ln(III) complexes, the X-ray crystal analysis revealed an unprecedented pseudo-achiral dodecahedron (DD-8 (D _2d)), whereas in CHCl ₃ solution, the exciton CD and ¹⁹F NMR spectra showed a novel chiral Δ-SAPR-8 (C ₄) configuration which is stereospecifically formed by a trapped Na ⁺ ion with Na ⁺⋯FC (fluorocarbon) interactions.

Original language	English
Pages (from-to)	6111-6113
Number of pages	3
Journal	Inorganic Chemistry
Volume	45
Issue number	16
DOIs	https://doi.org/10.1021/ic0606633
Publication status	Published - Aug 7 2006
Externally published	Yes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry

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Novel configurational structures of sodium tetrakis(3-heptafluorobutylryl- (+)-camphorato) Ln(III) complexes with a trapped Na ⁺ by Na ⁺⋯FC interactions in the solid state and in solution. / Shirotani, Dai; Suzuki, Takayoshi; Kaizaki, Sumio.
In: Inorganic Chemistry, Vol. 45, No. 16, 07.08.2006, p. 6111-6113.

Research output: Contribution to journal › Article › peer-review

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AU - Suzuki, Takayoshi

AU - Kaizaki, Sumio

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Novel configurational structures of sodium tetrakis(3-heptafluorobutylryl- (+)-camphorato) Ln(III) complexes with a trapped Na ⁺ by Na ⁺⋯FC interactions in the solid state and in solution

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