One-pot procedure for the introduction of three different bonds onto terminal alkynes through N-sulfonyl-1,2,3-triazole intermediates

Tomoya Miura; Takamasa Tanaka; Tsuneaki Biyajima; Akira Yada; Masahiro Murakami

doi:10.1002/anie.201209603

One-pot procedure for the introduction of three different bonds onto terminal alkynes through N-sulfonyl-1,2,3-triazole intermediates

Tomoya Miura, Takamasa Tanaka, Tsuneaki Biyajima, Akira Yada, Masahiro Murakami

Research output: Contribution to journal › Article › peer-review

151 Citations (Scopus)

Abstract

Triple strike: Copper(I) and rhodium(II) complexes can cooperate to facilely convert terminal alkynes into α-allyl-α-amino ketones through triazole intermediates. This synthetic process achieves the regioselective multifunctionalization of terminal alkynes with the formation of C-C, C-O, and C-N bonds in one pot.

Original language	English
Pages (from-to)	3883-3886
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	52
Issue number	14
DOIs	https://doi.org/10.1002/anie.201209603
Publication status	Published - Apr 2 2013
Externally published	Yes

Keywords

allylation
copper
rhodium
terminal alkynes
triazoles

ASJC Scopus subject areas

Catalysis
Chemistry(all)

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10.1002/anie.201209603

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abstract = "Triple strike: Copper(I) and rhodium(II) complexes can cooperate to facilely convert terminal alkynes into α-allyl-α-amino ketones through triazole intermediates. This synthetic process achieves the regioselective multifunctionalization of terminal alkynes with the formation of C-C, C-O, and C-N bonds in one pot.",

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AU - Yada, Akira

AU - Murakami, Masahiro

PY - 2013/4/2

Y1 - 2013/4/2

N2 - Triple strike: Copper(I) and rhodium(II) complexes can cooperate to facilely convert terminal alkynes into α-allyl-α-amino ketones through triazole intermediates. This synthetic process achieves the regioselective multifunctionalization of terminal alkynes with the formation of C-C, C-O, and C-N bonds in one pot.

AB - Triple strike: Copper(I) and rhodium(II) complexes can cooperate to facilely convert terminal alkynes into α-allyl-α-amino ketones through triazole intermediates. This synthetic process achieves the regioselective multifunctionalization of terminal alkynes with the formation of C-C, C-O, and C-N bonds in one pot.

KW - allylation

KW - copper

KW - rhodium

KW - terminal alkynes

KW - triazoles

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One-pot procedure for the introduction of three different bonds onto terminal alkynes through N-sulfonyl-1,2,3-triazole intermediates

Abstract

Keywords

ASJC Scopus subject areas

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