One-pot synthesis of 2-arylthio-2-cyclohexenone derivatives by the Diels-Alder reaction of 4-arylthio-3-hydroxy-2-pyrones

Takuzo Komiyama; Yutaka Takaguchi; Sadao Tsuboi

doi:10.1080/00397910701392434

One-pot synthesis of 2-arylthio-2-cyclohexenone derivatives by the Diels-Alder reaction of 4-arylthio-3-hydroxy-2-pyrones

Takuzo Komiyama, Yutaka Takaguchi, Sadao Tsuboi

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

The base-catalyzed Diels-Alder reactions of 4-arylthio-3-hydroxy-2-pyrones are reported. Treatment of 4-arylthio-3-hydroxy-2-pyrones and dienophiles with triethylamine gave 2-arylthio-2-cyclohexenone derivatives by the Diels-Alder reaction involving a decarboxylation in excellent to reasonable yields.

Original language	English
Pages (from-to)	2131-2136
Number of pages	6
Journal	Synthetic Communications
Volume	37
Issue number	13
DOIs	https://doi.org/10.1080/00397910701392434
Publication status	Published - Jan 1 2007

Keywords

2-arylthio-2-cyclohexenones
3-hydroxy-2-pyrones
Decarboxylation
Diels-Alder reaction
One-pot reaction

ASJC Scopus subject areas

Organic Chemistry

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10.1080/00397910701392434

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title = "One-pot synthesis of 2-arylthio-2-cyclohexenone derivatives by the Diels-Alder reaction of 4-arylthio-3-hydroxy-2-pyrones",

abstract = "The base-catalyzed Diels-Alder reactions of 4-arylthio-3-hydroxy-2-pyrones are reported. Treatment of 4-arylthio-3-hydroxy-2-pyrones and dienophiles with triethylamine gave 2-arylthio-2-cyclohexenone derivatives by the Diels-Alder reaction involving a decarboxylation in excellent to reasonable yields.",

keywords = "2-arylthio-2-cyclohexenones, 3-hydroxy-2-pyrones, Decarboxylation, Diels-Alder reaction, One-pot reaction",

author = "Takuzo Komiyama and Yutaka Takaguchi and Sadao Tsuboi",

year = "2007",

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doi = "10.1080/00397910701392434",

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T1 - One-pot synthesis of 2-arylthio-2-cyclohexenone derivatives by the Diels-Alder reaction of 4-arylthio-3-hydroxy-2-pyrones

AU - Komiyama, Takuzo

AU - Takaguchi, Yutaka

AU - Tsuboi, Sadao

PY - 2007/1/1

Y1 - 2007/1/1

N2 - The base-catalyzed Diels-Alder reactions of 4-arylthio-3-hydroxy-2-pyrones are reported. Treatment of 4-arylthio-3-hydroxy-2-pyrones and dienophiles with triethylamine gave 2-arylthio-2-cyclohexenone derivatives by the Diels-Alder reaction involving a decarboxylation in excellent to reasonable yields.

AB - The base-catalyzed Diels-Alder reactions of 4-arylthio-3-hydroxy-2-pyrones are reported. Treatment of 4-arylthio-3-hydroxy-2-pyrones and dienophiles with triethylamine gave 2-arylthio-2-cyclohexenone derivatives by the Diels-Alder reaction involving a decarboxylation in excellent to reasonable yields.

KW - 2-arylthio-2-cyclohexenones

KW - 3-hydroxy-2-pyrones

KW - Decarboxylation

KW - Diels-Alder reaction

KW - One-pot reaction

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ER -

One-pot synthesis of 2-arylthio-2-cyclohexenone derivatives by the Diels-Alder reaction of 4-arylthio-3-hydroxy-2-pyrones

Abstract

Keywords

ASJC Scopus subject areas

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