Oxidative desulfurization-fluorination of 1-substituted 2,2,2-tris(methylthio)ethanol induces difluorination under oxidation or rearrangement

Manabu Kuroboshi; Satoru Furuta; Tamejiro Hiyama

doi:10.1016/0040-4039(95)01234-9

Oxidative desulfurization-fluorination of 1-substituted 2,2,2-tris(methylthio)ethanol induces difluorination under oxidation or rearrangement

Manabu Kuroboshi
, Satoru Furuta
, Tamejiro Hiyama

Research output: Contribution to journal › Article › peer-review

18 Citations (Scopus)

Abstract

Oxidative desulfurization-fluorination of RCH(OH)C(SMe)₃ using n-Bu₄NH₂F₃ and 1,3-dibromo-5,5-dimethylhydantoin gave RC(O)CF₂SMe, whereas treatment of the same substrates with Et₂NSF₃ afforded RCH(SMe)CF₂SMe.

Original language	English
Pages (from-to)	6121-6122
Number of pages	2
Journal	Tetrahedron Letters
Volume	36
Issue number	34
DOIs	https://doi.org/10.1016/0040-4039(95)01234-9
Publication status	Published - Aug 21 1995
Externally published	Yes

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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@article{359046c35a93419299247b2d2e4a5ae8,

title = "Oxidative desulfurization-fluorination of 1-substituted 2,2,2-tris(methylthio)ethanol induces difluorination under oxidation or rearrangement",

abstract = "Oxidative desulfurization-fluorination of RCH(OH)C(SMe)3 using n-Bu4NH2F3 and 1,3-dibromo-5,5-dimethylhydantoin gave RC(O)CF2SMe, whereas treatment of the same substrates with Et2NSF3 afforded RCH(SMe)CF2SMe.",

author = "Manabu Kuroboshi and Satoru Furuta and Tamejiro Hiyama",

year = "1995",

month = aug,

day = "21",

doi = "10.1016/0040-4039(95)01234-9",

language = "English",

volume = "36",

pages = "6121--6122",

journal = "Tetrahedron Letters",

issn = "0040-4039",

publisher = "Elsevier Ltd",

number = "34",

}

TY - JOUR

T1 - Oxidative desulfurization-fluorination of 1-substituted 2,2,2-tris(methylthio)ethanol induces difluorination under oxidation or rearrangement

AU - Kuroboshi, Manabu

AU - Furuta, Satoru

AU - Hiyama, Tamejiro

PY - 1995/8/21

Y1 - 1995/8/21

N2 - Oxidative desulfurization-fluorination of RCH(OH)C(SMe)3 using n-Bu4NH2F3 and 1,3-dibromo-5,5-dimethylhydantoin gave RC(O)CF2SMe, whereas treatment of the same substrates with Et2NSF3 afforded RCH(SMe)CF2SMe.

AB - Oxidative desulfurization-fluorination of RCH(OH)C(SMe)3 using n-Bu4NH2F3 and 1,3-dibromo-5,5-dimethylhydantoin gave RC(O)CF2SMe, whereas treatment of the same substrates with Et2NSF3 afforded RCH(SMe)CF2SMe.

UR - https://www.scopus.com/pages/publications/0029154520

UR - https://www.scopus.com/pages/publications/0029154520#tab=citedBy

U2 - 10.1016/0040-4039(95)01234-9

DO - 10.1016/0040-4039(95)01234-9

M3 - Article

AN - SCOPUS:0029154520

SN - 0040-4039

VL - 36

SP - 6121

EP - 6122

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 34

ER -

Oxidative desulfurization-fluorination of 1-substituted 2,2,2-tris(methylthio)ethanol induces difluorination under oxidation or rearrangement

Abstract

ASJC Scopus subject areas

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