Pd/NHC-catalyzed cross-coupling reactions of nitroarenes

Myuto Kashihara; Rong Lin Zhong; Kazuhiko Semba; Shigeyoshi Sakaki; Yoshiaki Nakao

doi:10.1039/c9cc05055h

Pd/NHC-catalyzed cross-coupling reactions of nitroarenes

Myuto Kashihara, Rong Lin Zhong, Kazuhiko Semba, Shigeyoshi Sakaki, Yoshiaki Nakao

Research output: Contribution to journal › Article › peer-review

38 Citations (Scopus)

Abstract

N-Heterocyclic carbene (NHC) ligands effective for the cross-coupling of nitroarenes were identified. A rational design of the NHC ligand structures enabled significant reduction of catalyst loadings compared with the previous system employing BrettPhos as a phosphine ligand. Experimental and theoretical studies to compare these ligands gave some insights into high activity of the newly developed NHC ligands.

Original language	English
Pages (from-to)	9291-9294
Number of pages	4
Journal	Chemical Communications
Volume	55
Issue number	63
DOIs	https://doi.org/10.1039/c9cc05055h
Publication status	Published - 2019
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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title = "Pd/NHC-catalyzed cross-coupling reactions of nitroarenes",

abstract = "N-Heterocyclic carbene (NHC) ligands effective for the cross-coupling of nitroarenes were identified. A rational design of the NHC ligand structures enabled significant reduction of catalyst loadings compared with the previous system employing BrettPhos as a phosphine ligand. Experimental and theoretical studies to compare these ligands gave some insights into high activity of the newly developed NHC ligands.",

author = "Myuto Kashihara and Zhong, {Rong Lin} and Kazuhiko Semba and Shigeyoshi Sakaki and Yoshiaki Nakao",

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language = "English",

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T1 - Pd/NHC-catalyzed cross-coupling reactions of nitroarenes

AU - Kashihara, Myuto

AU - Zhong, Rong Lin

AU - Semba, Kazuhiko

AU - Sakaki, Shigeyoshi

AU - Nakao, Yoshiaki

N1 - Funding Information: This work was supported by the ‘‘JST CREST program Grant Number JPMJCR14L3 in Establishment of Molecular Technology towards the Creation of New Functions’’, the ‘‘JSPS KAKENHI Grant Number JP15H05799 in Precisely Designed Catalysts with Customized Scaffolding’’, and TOSOH corporation. Publisher Copyright: © 2019 The Royal Society of Chemistry.

PY - 2019

Y1 - 2019

N2 - N-Heterocyclic carbene (NHC) ligands effective for the cross-coupling of nitroarenes were identified. A rational design of the NHC ligand structures enabled significant reduction of catalyst loadings compared with the previous system employing BrettPhos as a phosphine ligand. Experimental and theoretical studies to compare these ligands gave some insights into high activity of the newly developed NHC ligands.

AB - N-Heterocyclic carbene (NHC) ligands effective for the cross-coupling of nitroarenes were identified. A rational design of the NHC ligand structures enabled significant reduction of catalyst loadings compared with the previous system employing BrettPhos as a phosphine ligand. Experimental and theoretical studies to compare these ligands gave some insights into high activity of the newly developed NHC ligands.

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JO - Chemical Communications

JF - Chemical Communications

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ER -

Pd/NHC-catalyzed cross-coupling reactions of nitroarenes

Abstract

ASJC Scopus subject areas

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