Peroxidase-like activity of ion exchange resins modified with metal- porphine in fluorescent flow injection analysis

Akimasa Iwado; Masaki Mifune; Takahiro Hazawa; Takashi Mukuno; Junko Oda; Noriko Motohashi; Yutaka Saito

doi:10.2116/analsci.15.841

Peroxidase-like activity of ion exchange resins modified with metal- porphine in fluorescent flow injection analysis

Akimasa Iwado, Masaki Mifune, Takahiro Hazawa, Takashi Mukuno, Junko Oda, Noriko Motohashi, Yutaka Saito

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

Peroxidase-like activity of anion-exchange resins modified With rnetal- tetrakis(sulfophenyl)porphine (M-TSPP(r), M=Fe³⁺, Co³⁺ and Mn³⁺) were evaluated in the flow injection analysis of hydrogen peroxide using a fluorescent dimmer-formation reaction from chromogens, such as tyramine. A column (2.1 mmx50 mm) packed with Fe³⁺-TSPP(r) and a tube (0.8 mmx50 mm) packed with Mn³⁺-TSPP(r) accelerated the dimmer-formation reaction, indicating that they exhibit peroxidase-like activity just like the peroxidase-immobilized-column in the flow injection system.

Original language	English
Pages (from-to)	841-846
Number of pages	6
Journal	Analytical Sciences
Volume	15
Issue number	9
DOIs	https://doi.org/10.2116/analsci.15.841
Publication status	Published - Sept 1999

Keywords

Flow injection analysis
Fluorescence
Glucose
Hydrogen per-oxide
Metal-porphine
Modified resin
Peroxidase-like activity

ASJC Scopus subject areas

Analytical Chemistry

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10.2116/analsci.15.841

Cite this

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title = "Peroxidase-like activity of ion exchange resins modified with metal- porphine in fluorescent flow injection analysis",

abstract = "Peroxidase-like activity of anion-exchange resins modified With rnetal- tetrakis(sulfophenyl)porphine (M-TSPP(r), M=Fe3+, Co3+ and Mn3+) were evaluated in the flow injection analysis of hydrogen peroxide using a fluorescent dimmer-formation reaction from chromogens, such as tyramine. A column (2.1 mmx50 mm) packed with Fe3+-TSPP(r) and a tube (0.8 mmx50 mm) packed with Mn3+-TSPP(r) accelerated the dimmer-formation reaction, indicating that they exhibit peroxidase-like activity just like the peroxidase-immobilized-column in the flow injection system.",

keywords = "Flow injection analysis, Fluorescence, Glucose, Hydrogen per-oxide, Metal-porphine, Modified resin, Peroxidase-like activity",

author = "Akimasa Iwado and Masaki Mifune and Takahiro Hazawa and Takashi Mukuno and Junko Oda and Noriko Motohashi and Yutaka Saito",

year = "1999",

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volume = "15",

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journal = "Analytical Sciences",

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publisher = "Japan Society for Analytical Chemistry",

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T1 - Peroxidase-like activity of ion exchange resins modified with metal- porphine in fluorescent flow injection analysis

AU - Iwado, Akimasa

AU - Mifune, Masaki

AU - Hazawa, Takahiro

AU - Mukuno, Takashi

AU - Oda, Junko

AU - Motohashi, Noriko

AU - Saito, Yutaka

PY - 1999/9

Y1 - 1999/9

N2 - Peroxidase-like activity of anion-exchange resins modified With rnetal- tetrakis(sulfophenyl)porphine (M-TSPP(r), M=Fe3+, Co3+ and Mn3+) were evaluated in the flow injection analysis of hydrogen peroxide using a fluorescent dimmer-formation reaction from chromogens, such as tyramine. A column (2.1 mmx50 mm) packed with Fe3+-TSPP(r) and a tube (0.8 mmx50 mm) packed with Mn3+-TSPP(r) accelerated the dimmer-formation reaction, indicating that they exhibit peroxidase-like activity just like the peroxidase-immobilized-column in the flow injection system.

AB - Peroxidase-like activity of anion-exchange resins modified With rnetal- tetrakis(sulfophenyl)porphine (M-TSPP(r), M=Fe3+, Co3+ and Mn3+) were evaluated in the flow injection analysis of hydrogen peroxide using a fluorescent dimmer-formation reaction from chromogens, such as tyramine. A column (2.1 mmx50 mm) packed with Fe3+-TSPP(r) and a tube (0.8 mmx50 mm) packed with Mn3+-TSPP(r) accelerated the dimmer-formation reaction, indicating that they exhibit peroxidase-like activity just like the peroxidase-immobilized-column in the flow injection system.

KW - Flow injection analysis

KW - Fluorescence

KW - Glucose

KW - Hydrogen per-oxide

KW - Metal-porphine

KW - Modified resin

KW - Peroxidase-like activity

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JO - Analytical Sciences

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ER -

Peroxidase-like activity of ion exchange resins modified with metal- porphine in fluorescent flow injection analysis

Abstract

Keywords

ASJC Scopus subject areas

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