TY - JOUR
T1 - Photoproduct distribution spectrum of the sensitized photoreaction of 1,4-p-benzenonaphthalene
AU - Kimura, Masaru
AU - Nukada, Katsumi
AU - Satake, Kyosuke
AU - Morosawa, Shiro
PY - 1986/12/1
Y1 - 1986/12/1
N2 - A correlation between the type of the photoproducts of 1,4,9,10,11,12- hexahydro-1,4-p-benzenonaphthalene (1) and triplet carbonyl and non-carbonyl sensitizers has been investigated. Electron transfer from the alkene moiety of (1) to excited sensitizers may cause the formation of naphthalene. The cage compound (2) was formed via energy transfer from excited sensitizers (E t ≥ 71 kcal/mol) to the triplet state (T1) of (1). The irradiation of benzaldehyde and (1) gave the cage compound (2) and (2RS, 2aRS, 3SR, 9RS)-2a,3,8,8a,9,10,11,12-octahydro-3,8-p-benzeno-2H-naphth[2,3-b]oxete (3).
AB - A correlation between the type of the photoproducts of 1,4,9,10,11,12- hexahydro-1,4-p-benzenonaphthalene (1) and triplet carbonyl and non-carbonyl sensitizers has been investigated. Electron transfer from the alkene moiety of (1) to excited sensitizers may cause the formation of naphthalene. The cage compound (2) was formed via energy transfer from excited sensitizers (E t ≥ 71 kcal/mol) to the triplet state (T1) of (1). The irradiation of benzaldehyde and (1) gave the cage compound (2) and (2RS, 2aRS, 3SR, 9RS)-2a,3,8,8a,9,10,11,12-octahydro-3,8-p-benzeno-2H-naphth[2,3-b]oxete (3).
UR - http://www.scopus.com/inward/record.url?scp=37049078390&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=37049078390&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:37049078390
SN - 1472-7781
SP - 885
EP - 888
JO - Journal of the Chemical Society, Perkin Transactions 1
JF - Journal of the Chemical Society, Perkin Transactions 1
ER -