Preparation and electrochemical and optical properties of tetrakis(dithiaselenolo)phthalocyanine

Takeshi Kimura, Toshiharu Namauo, Akio Yamakawa, Yutaka Takaguchi

    Research output: Contribution to journalArticlepeer-review

    2 Citations (Scopus)

    Abstract

    Four o-xylylene groups of phthalocyanine (2) were removed by Birch reduction and the generated octathiolate anions were then reacted with Se to give tetrakis(dithiaselenolo)phthalocyanine (3). The dication generated from 3 in CHCl3/TFA was determined with UV-vis and NMR spectroscopy.

    Original languageEnglish
    Pages (from-to)1081-1086
    Number of pages6
    JournalHeterocycles
    Volume79
    Issue numberC
    DOIs
    Publication statusPublished - 2009

    Keywords

    • Dithiaselenole Ring
    • NMR Spectra
    • Phthalocyanine
    • Protonation
    • UV-Vis Spectra

    ASJC Scopus subject areas

    • Analytical Chemistry
    • Pharmacology
    • Organic Chemistry

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