TY - JOUR
T1 - Preparation and optical and electrochemical properties of phthalocyanines with the TtF unit
AU - Kimura, Takeshi
AU - Takahashi, Nobuhiro
AU - Tajima, Tomoyuki
AU - Takaguchi, Yutaka
PY - 2013/4/1
Y1 - 2013/4/1
N2 - Tetrathiafluvalene (TTF)-annulated symmetrical and unsymmetrical phthalocyanines (4), (5), and (6) were prepared from 3,6-dioctylphthalonitrile (1) with a TTF unit, 4,5-dioctyloxyphthalonitrile (2), and 3,6- dioctyloxyphthalonitrile (3). Tetra-TTF-annulated phthalocyanine (4) and iodine produced an electron transfer complex which showed a radical cationic character.
AB - Tetrathiafluvalene (TTF)-annulated symmetrical and unsymmetrical phthalocyanines (4), (5), and (6) were prepared from 3,6-dioctylphthalonitrile (1) with a TTF unit, 4,5-dioctyloxyphthalonitrile (2), and 3,6- dioctyloxyphthalonitrile (3). Tetra-TTF-annulated phthalocyanine (4) and iodine produced an electron transfer complex which showed a radical cationic character.
KW - Phthalocyanine
KW - TTF
KW - UV-vis spectroscopy
KW - electron transfer
KW - radical cation
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U2 - 10.1080/10426507.2012.729115
DO - 10.1080/10426507.2012.729115
M3 - Article
AN - SCOPUS:84879074630
SN - 1042-6507
VL - 188
SP - 408
EP - 412
JO - Phosphorus, Sulfur and Silicon and the Related Elements
JF - Phosphorus, Sulfur and Silicon and the Related Elements
IS - 4
ER -