Preparation of aluminum oxide-hybridized hydroxyapatite powder by the sol-gel method

Eiji Fujii; Koji Kawabata; Hideyuki Yoshimatsu; Kanji Tsuru; Satoshi Hayakawa; Akiyoshi Osaka

doi:10.2109/jcersj.113.241

Preparation of aluminum oxide-hybridized hydroxyapatite powder by the sol-gel method

Eiji Fujii, Koji Kawabata, Hideyuki Yoshimatsu, Kanji Tsuru, Satoshi Hayakawa, Akiyoshi Osaka

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

Hydroxyapatite powders (HAp; Ca₁₀(PO₄) ₆(OH)₂) hybridized with 0-5 mass % Al₂O ₃ were prepared from calcium hydroxide and di-aminonium hydrogenphosphate by a wet chemical synthesis. Ethylacetoacetate Aluminum Diisopropoxide (Al(OC₃H₇)₂(C₆H ₉O₃)) was used as a source for aluminum oxide. The obtained powders were characterized by X-ray diffraction (XRD), Brunauer-Emmett-Teller (BET) specific surface area measurement, and magic angle spinning-nuclear magnetic resonance spectroscopy (MAS-NMR). The X-ray diffraction patterns showed no Al₂O₃-peaks irrespective of Al₂O₃ content, suggesting that the Al₂O ₃-hybridized HAp powders were single phase. The Al₂O ₃-hybridized HAp powder had larger specific surface area. According to MAS-NMR analysis, it was considered that the aluminum element existed as aluminum oxide, it was not substituted for the Ca²⁺, PO ₄^3-, or OH^- ions.

Original language	English
Pages (from-to)	241-244
Number of pages	4
Journal	Journal of the Ceramic Society of Japan
Volume	113
Issue number	1315
DOIs	https://doi.org/10.2109/jcersj.113.241
Publication status	Published - Mar 2005

Keywords

Aluminum
Biomaterials
Hybrid material
Hydroxyapatite
MAS-NMR
Sol-gel method

ASJC Scopus subject areas

Ceramics and Composites
Chemistry(all)
Condensed Matter Physics
Materials Chemistry

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title = "Preparation of aluminum oxide-hybridized hydroxyapatite powder by the sol-gel method",

abstract = "Hydroxyapatite powders (HAp; Ca10(PO4) 6(OH)2) hybridized with 0-5 mass % Al2O 3 were prepared from calcium hydroxide and di-aminonium hydrogenphosphate by a wet chemical synthesis. Ethylacetoacetate Aluminum Diisopropoxide (Al(OC3H7)2(C6H 9O3)) was used as a source for aluminum oxide. The obtained powders were characterized by X-ray diffraction (XRD), Brunauer-Emmett-Teller (BET) specific surface area measurement, and magic angle spinning-nuclear magnetic resonance spectroscopy (MAS-NMR). The X-ray diffraction patterns showed no Al2O3-peaks irrespective of Al2O3 content, suggesting that the Al2O 3-hybridized HAp powders were single phase. The Al2O 3-hybridized HAp powder had larger specific surface area. According to MAS-NMR analysis, it was considered that the aluminum element existed as aluminum oxide, it was not substituted for the Ca2+, PO 43-, or OH- ions.",

keywords = "Aluminum, Biomaterials, Hybrid material, Hydroxyapatite, MAS-NMR, Sol-gel method",

author = "Eiji Fujii and Koji Kawabata and Hideyuki Yoshimatsu and Kanji Tsuru and Satoshi Hayakawa and Akiyoshi Osaka",

year = "2005",

month = mar,

doi = "10.2109/jcersj.113.241",

language = "English",

volume = "113",

pages = "241--244",

journal = "Journal of the Ceramic Society of Japan",

issn = "0914-5400",

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T1 - Preparation of aluminum oxide-hybridized hydroxyapatite powder by the sol-gel method

AU - Fujii, Eiji

AU - Kawabata, Koji

AU - Yoshimatsu, Hideyuki

AU - Tsuru, Kanji

AU - Hayakawa, Satoshi

AU - Osaka, Akiyoshi

PY - 2005/3

Y1 - 2005/3

N2 - Hydroxyapatite powders (HAp; Ca10(PO4) 6(OH)2) hybridized with 0-5 mass % Al2O 3 were prepared from calcium hydroxide and di-aminonium hydrogenphosphate by a wet chemical synthesis. Ethylacetoacetate Aluminum Diisopropoxide (Al(OC3H7)2(C6H 9O3)) was used as a source for aluminum oxide. The obtained powders were characterized by X-ray diffraction (XRD), Brunauer-Emmett-Teller (BET) specific surface area measurement, and magic angle spinning-nuclear magnetic resonance spectroscopy (MAS-NMR). The X-ray diffraction patterns showed no Al2O3-peaks irrespective of Al2O3 content, suggesting that the Al2O 3-hybridized HAp powders were single phase. The Al2O 3-hybridized HAp powder had larger specific surface area. According to MAS-NMR analysis, it was considered that the aluminum element existed as aluminum oxide, it was not substituted for the Ca2+, PO 43-, or OH- ions.

AB - Hydroxyapatite powders (HAp; Ca10(PO4) 6(OH)2) hybridized with 0-5 mass % Al2O 3 were prepared from calcium hydroxide and di-aminonium hydrogenphosphate by a wet chemical synthesis. Ethylacetoacetate Aluminum Diisopropoxide (Al(OC3H7)2(C6H 9O3)) was used as a source for aluminum oxide. The obtained powders were characterized by X-ray diffraction (XRD), Brunauer-Emmett-Teller (BET) specific surface area measurement, and magic angle spinning-nuclear magnetic resonance spectroscopy (MAS-NMR). The X-ray diffraction patterns showed no Al2O3-peaks irrespective of Al2O3 content, suggesting that the Al2O 3-hybridized HAp powders were single phase. The Al2O 3-hybridized HAp powder had larger specific surface area. According to MAS-NMR analysis, it was considered that the aluminum element existed as aluminum oxide, it was not substituted for the Ca2+, PO 43-, or OH- ions.

KW - Aluminum

KW - Biomaterials

KW - Hybrid material

KW - Hydroxyapatite

KW - MAS-NMR

KW - Sol-gel method

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JO - Journal of the Ceramic Society of Japan

JF - Journal of the Ceramic Society of Japan

IS - 1315

ER -

Preparation of aluminum oxide-hybridized hydroxyapatite powder by the sol-gel method

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Keywords

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