Pressure and temperature dependences of the structural properties of (formula presented) isomer I

Y. Takabayashi; Y. Kubozono; T. Kanbara; S. Fujiki; K. Shibata; Y. Haruyama; T. Hosokawa; Y. Rikiishi; S. Kashino

doi:10.1103/PhysRevB.65.073405

Pressure and temperature dependences of the structural properties of (formula presented) isomer I

Y. Takabayashi, Y. Kubozono, T. Kanbara, S. Fujiki, K. Shibata, Y. Haruyama, T. Hosokawa, Y. Rikiishi, S. Kashino

Research output: Contribution to journal › Article › peer-review

Abstract

Crystals of (formula presented) isomer I are studied by x-ray powder diffraction with synchrotron radiation in wide temperature and pressure regions. The isomer I of (formula presented) shows a simple cubic structure with lattice constant a of 15.85(3) Å at 298 K, while the isomer II shows a face-centered cubic structure with a of 15.75(4) Å. The structural phase transition of the second order is indicated for the isomer I at 300-310 K by the temperature dependence of x-ray diffraction and differential scanning calorimetry. Further, the pressure dependence of the lattice constant is studied for the isomer I up to 60 kbar, which can be fitted by a Murnaghan equation of state.

Original language	English
Pages (from-to)	1-4
Number of pages	4
Journal	Physical Review B - Condensed Matter and Materials Physics
Volume	65
Issue number	7
DOIs	https://doi.org/10.1103/PhysRevB.65.073405
Publication status	Published - Jan 1 2002
Externally published	Yes

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Condensed Matter Physics

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10.1103/PhysRevB.65.073405

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@article{9a1743412be84ed59c75e4678221c61a,

title = "Pressure and temperature dependences of the structural properties of (formula presented) isomer I",

abstract = "Crystals of (formula presented) isomer I are studied by x-ray powder diffraction with synchrotron radiation in wide temperature and pressure regions. The isomer I of (formula presented) shows a simple cubic structure with lattice constant a of 15.85(3) {\AA} at 298 K, while the isomer II shows a face-centered cubic structure with a of 15.75(4) {\AA}. The structural phase transition of the second order is indicated for the isomer I at 300-310 K by the temperature dependence of x-ray diffraction and differential scanning calorimetry. Further, the pressure dependence of the lattice constant is studied for the isomer I up to 60 kbar, which can be fitted by a Murnaghan equation of state.",

author = "Y. Takabayashi and Y. Kubozono and T. Kanbara and S. Fujiki and K. Shibata and Y. Haruyama and T. Hosokawa and Y. Rikiishi and S. Kashino",

year = "2002",

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doi = "10.1103/PhysRevB.65.073405",

language = "English",

volume = "65",

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journal = "Physical Review B-Condensed Matter",

issn = "1098-0121",

publisher = "American Physical Society",

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TY - JOUR

T1 - Pressure and temperature dependences of the structural properties of (formula presented) isomer I

AU - Takabayashi, Y.

AU - Kubozono, Y.

AU - Kanbara, T.

AU - Fujiki, S.

AU - Shibata, K.

AU - Haruyama, Y.

AU - Hosokawa, T.

AU - Rikiishi, Y.

AU - Kashino, S.

PY - 2002/1/1

Y1 - 2002/1/1

N2 - Crystals of (formula presented) isomer I are studied by x-ray powder diffraction with synchrotron radiation in wide temperature and pressure regions. The isomer I of (formula presented) shows a simple cubic structure with lattice constant a of 15.85(3) Å at 298 K, while the isomer II shows a face-centered cubic structure with a of 15.75(4) Å. The structural phase transition of the second order is indicated for the isomer I at 300-310 K by the temperature dependence of x-ray diffraction and differential scanning calorimetry. Further, the pressure dependence of the lattice constant is studied for the isomer I up to 60 kbar, which can be fitted by a Murnaghan equation of state.

AB - Crystals of (formula presented) isomer I are studied by x-ray powder diffraction with synchrotron radiation in wide temperature and pressure regions. The isomer I of (formula presented) shows a simple cubic structure with lattice constant a of 15.85(3) Å at 298 K, while the isomer II shows a face-centered cubic structure with a of 15.75(4) Å. The structural phase transition of the second order is indicated for the isomer I at 300-310 K by the temperature dependence of x-ray diffraction and differential scanning calorimetry. Further, the pressure dependence of the lattice constant is studied for the isomer I up to 60 kbar, which can be fitted by a Murnaghan equation of state.

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JO - Physical Review B-Condensed Matter

JF - Physical Review B-Condensed Matter

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Pressure and temperature dependences of the structural properties of (formula presented) isomer I

Abstract

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