TY - JOUR
T1 - Pyridylsilyl group-driven cross-coupling reactions
AU - Itami, Kenichiro
AU - Mitsudo, Koichi
AU - Nokami, Toshiki
AU - Kamei, Toshiyuki
AU - Koike, Tooru
AU - Yoshida, Jun ichi
N1 - Funding Information:
This research was supported by a Grant-in-Aid for Scientific Research from the Japan Society for the Promotion of Science, and the Mitsubishi Foundation. K.M. and T.N. thank the Japan Society for the Promotion of Science for Young Scientists. K.I. thanks Nissan Chemical Industries for the Award in Synthetic Organic Chemistry, Japan.
PY - 2002/7/1
Y1 - 2002/7/1
N2 - Summarized herein are the demonstrations that the use of 2-PyMe2Si group as a removable directing group is a powerful strategy for enhancing the efficiency of otherwise sluggish processes and for steering the course of the reaction by taking advantage of attractive substrate-catalyst interaction in the palladium-catalyzed cross-coupling chemistry. The 2-PyMe2Si group-driven Heck-type coupling, Hiyama-type coupling, Stille-type coupling, and allylic alkylation are described.
AB - Summarized herein are the demonstrations that the use of 2-PyMe2Si group as a removable directing group is a powerful strategy for enhancing the efficiency of otherwise sluggish processes and for steering the course of the reaction by taking advantage of attractive substrate-catalyst interaction in the palladium-catalyzed cross-coupling chemistry. The 2-PyMe2Si group-driven Heck-type coupling, Hiyama-type coupling, Stille-type coupling, and allylic alkylation are described.
KW - Cross-coupling reaction
KW - Pyridylsilyl group
KW - Removable directing group
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U2 - 10.1016/S0022-328X(02)01173-7
DO - 10.1016/S0022-328X(02)01173-7
M3 - Review article
AN - SCOPUS:0036643458
SN - 0022-328X
VL - 653
SP - 105
EP - 113
JO - Journal of Organometallic Chemistry
JF - Journal of Organometallic Chemistry
IS - 1-2
ER -