Reactivity of surface hydroxyl groups with metal complex compounds

T. Yamada; Y. Kuroda; A. Fukuoka; M. Ichikawa; K. Tanaka

doi:10.1016/0368-2048(90)80277-H

Reactivity of surface hydroxyl groups with metal complex compounds

T. Yamada, Y. Kuroda, A. Fukuoka, M. Ichikawa, K. Tanaka

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

The surface reaction of the adsorbed hydroxyl group OH(a) with Rh(CO)₂(π-C₃H₅) delivered from the gas phase: OH (a) + Rh(CO)₂(π-C₃H₅)(g) → O-Rh( CO )₂(a) + C₃H₆(a/g) has been studied on Ni(110), Ni(100) and ZnO(1010) mainly by HREELS and TPRS. On Ni(110), p(2×1)-OH(a) was completely diminished by adsorption of Rh(CO)₂(π-C₃H₅) below 300 K. C₃H₆ stayed on the surface after this reaction. On Zn(1010) OH(a) was deposited with surface defects indroduced by Ar ion bombardment. The same reaction occurred with OH(a) on ZnO(1010), but not completely on Ni(100) which was covered with oxide layers.

Original language	English
Pages (from-to)	845-854
Number of pages	10
Journal	Journal of Electron Spectroscopy and Related Phenomena
Volume	54-55
Issue number	C
DOIs	https://doi.org/10.1016/0368-2048(90)80277-H
Publication status	Published - 1990

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Radiation
Atomic and Molecular Physics, and Optics
Condensed Matter Physics
Spectroscopy
Physical and Theoretical Chemistry

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10.1016/0368-2048(90)80277-H

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@article{634adf79629f4c9b89de7ebb3cf67791,

title = "Reactivity of surface hydroxyl groups with metal complex compounds",

abstract = "The surface reaction of the adsorbed hydroxyl group OH(a) with Rh(CO)2(π-C3H5) delivered from the gas phase: OH (a) + Rh(CO)2(π-C3H5)(g) → O-Rh( CO )2(a) + C3H6(a/g) has been studied on Ni(110), Ni(100) and ZnO(1010) mainly by HREELS and TPRS. On Ni(110), p(2×1)-OH(a) was completely diminished by adsorption of Rh(CO)2(π-C3H5) below 300 K. C3H6 stayed on the surface after this reaction. On Zn(1010) OH(a) was deposited with surface defects indroduced by Ar ion bombardment. The same reaction occurred with OH(a) on ZnO(1010), but not completely on Ni(100) which was covered with oxide layers.",

author = "T. Yamada and Y. Kuroda and A. Fukuoka and M. Ichikawa and K. Tanaka",

year = "1990",

doi = "10.1016/0368-2048(90)80277-H",

language = "English",

volume = "54-55",

pages = "845--854",

journal = "Journal of Electron Spectroscopy and Related Phenomena",

issn = "0368-2048",

publisher = "Elsevier",

number = "C",

}

TY - JOUR

T1 - Reactivity of surface hydroxyl groups with metal complex compounds

AU - Yamada, T.

AU - Kuroda, Y.

AU - Fukuoka, A.

AU - Ichikawa, M.

AU - Tanaka, K.

PY - 1990

Y1 - 1990

N2 - The surface reaction of the adsorbed hydroxyl group OH(a) with Rh(CO)2(π-C3H5) delivered from the gas phase: OH (a) + Rh(CO)2(π-C3H5)(g) → O-Rh( CO )2(a) + C3H6(a/g) has been studied on Ni(110), Ni(100) and ZnO(1010) mainly by HREELS and TPRS. On Ni(110), p(2×1)-OH(a) was completely diminished by adsorption of Rh(CO)2(π-C3H5) below 300 K. C3H6 stayed on the surface after this reaction. On Zn(1010) OH(a) was deposited with surface defects indroduced by Ar ion bombardment. The same reaction occurred with OH(a) on ZnO(1010), but not completely on Ni(100) which was covered with oxide layers.

AB - The surface reaction of the adsorbed hydroxyl group OH(a) with Rh(CO)2(π-C3H5) delivered from the gas phase: OH (a) + Rh(CO)2(π-C3H5)(g) → O-Rh( CO )2(a) + C3H6(a/g) has been studied on Ni(110), Ni(100) and ZnO(1010) mainly by HREELS and TPRS. On Ni(110), p(2×1)-OH(a) was completely diminished by adsorption of Rh(CO)2(π-C3H5) below 300 K. C3H6 stayed on the surface after this reaction. On Zn(1010) OH(a) was deposited with surface defects indroduced by Ar ion bombardment. The same reaction occurred with OH(a) on ZnO(1010), but not completely on Ni(100) which was covered with oxide layers.

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U2 - 10.1016/0368-2048(90)80277-H

DO - 10.1016/0368-2048(90)80277-H

M3 - Article

AN - SCOPUS:44949269181

SN - 0368-2048

VL - 54-55

SP - 845

EP - 854

JO - Journal of Electron Spectroscopy and Related Phenomena

JF - Journal of Electron Spectroscopy and Related Phenomena

IS - C

ER -

Reactivity of surface hydroxyl groups with metal complex compounds

Abstract

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