Recent structural investigations of metallic polymers

J. P. Pouget; Z. Oblakowski; Y. Nogami; P. A. Albouy; M. Laridjani; E. J. Oh; Y. Min; A. G. MacDiarmid; J. Tsukamoto; T. Ishiguro; A. J. Epstein

doi:10.1016/0379-6779(94)90174-0

Recent structural investigations of metallic polymers

J. P. Pouget, Z. Oblakowski, Y. Nogami, P. A. Albouy, M. Laridjani, E. J. Oh, Y. Min, A. G. MacDiarmid, J. Tsukamoto, T. Ishiguro, A. J. Epstein

Research output: Contribution to journal › Article › peer-review

105 Citations (Scopus)

Abstract

Recent structural studies of the undoped and iodine-doped polyacetylenes (prepared by the Tsukamoto and co-workers method), PF₆^--doped polypyrrole and polyaniline emeraldine base and (hydrochloric acid and camphorsulfonic acid) salts are presented. Some key features of the polymer chain array and its evolution with the conditions of preparation are emphasized. Special attention has been devoted to characterization of the various sources of structural disorder in the relationship with high conductivity and related properties exhibited by these three families of polymers. Variation in the structural order in both crystalline and amorphous regions correlates directly with the electrical and optical properties of the metallic state.

Original language	English
Pages (from-to)	131-140
Number of pages	10
Journal	Synthetic Metals
Volume	65
Issue number	2-3
DOIs	https://doi.org/10.1016/0379-6779(94)90174-0
Publication status	Published - Aug 1994
Externally published	Yes

Keywords

Metallic polymers
Structure

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Condensed Matter Physics
Mechanics of Materials
Mechanical Engineering
Metals and Alloys
Materials Chemistry

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10.1016/0379-6779(94)90174-0

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title = "Recent structural investigations of metallic polymers",

abstract = "Recent structural studies of the undoped and iodine-doped polyacetylenes (prepared by the Tsukamoto and co-workers method), PF6--doped polypyrrole and polyaniline emeraldine base and (hydrochloric acid and camphorsulfonic acid) salts are presented. Some key features of the polymer chain array and its evolution with the conditions of preparation are emphasized. Special attention has been devoted to characterization of the various sources of structural disorder in the relationship with high conductivity and related properties exhibited by these three families of polymers. Variation in the structural order in both crystalline and amorphous regions correlates directly with the electrical and optical properties of the metallic state.",

keywords = "Metallic polymers, Structure",

author = "Pouget, {J. P.} and Z. Oblakowski and Y. Nogami and Albouy, {P. A.} and M. Laridjani and Oh, {E. J.} and Y. Min and MacDiarmid, {A. G.} and J. Tsukamoto and T. Ishiguro and Epstein, {A. J.}",

note = "Funding Information: This work was partly supportedb y a grant for an InternationaJol int ResearchP rojectfrom The New Energy and IndustrialT echnologyD evelopmenOt r-ganization(N EDO, Japan), by an 'Action Incitative' CNRS-NSF, by NSF INT Grant No. 90-16586a ndby",

year = "1994",

month = aug,

doi = "10.1016/0379-6779(94)90174-0",

language = "English",

volume = "65",

pages = "131--140",

journal = "Synthetic Metals",

issn = "0379-6779",

publisher = "Elsevier BV",

number = "2-3",

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TY - JOUR

T1 - Recent structural investigations of metallic polymers

AU - Pouget, J. P.

AU - Oblakowski, Z.

AU - Nogami, Y.

AU - Albouy, P. A.

AU - Laridjani, M.

AU - Oh, E. J.

AU - Min, Y.

AU - MacDiarmid, A. G.

AU - Tsukamoto, J.

AU - Ishiguro, T.

AU - Epstein, A. J.

N1 - Funding Information: This work was partly supportedb y a grant for an InternationaJol int ResearchP rojectfrom The New Energy and IndustrialT echnologyD evelopmenOt r-ganization(N EDO, Japan), by an 'Action Incitative' CNRS-NSF, by NSF INT Grant No. 90-16586a ndby

PY - 1994/8

Y1 - 1994/8

N2 - Recent structural studies of the undoped and iodine-doped polyacetylenes (prepared by the Tsukamoto and co-workers method), PF6--doped polypyrrole and polyaniline emeraldine base and (hydrochloric acid and camphorsulfonic acid) salts are presented. Some key features of the polymer chain array and its evolution with the conditions of preparation are emphasized. Special attention has been devoted to characterization of the various sources of structural disorder in the relationship with high conductivity and related properties exhibited by these three families of polymers. Variation in the structural order in both crystalline and amorphous regions correlates directly with the electrical and optical properties of the metallic state.

AB - Recent structural studies of the undoped and iodine-doped polyacetylenes (prepared by the Tsukamoto and co-workers method), PF6--doped polypyrrole and polyaniline emeraldine base and (hydrochloric acid and camphorsulfonic acid) salts are presented. Some key features of the polymer chain array and its evolution with the conditions of preparation are emphasized. Special attention has been devoted to characterization of the various sources of structural disorder in the relationship with high conductivity and related properties exhibited by these three families of polymers. Variation in the structural order in both crystalline and amorphous regions correlates directly with the electrical and optical properties of the metallic state.

KW - Metallic polymers

KW - Structure

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U2 - 10.1016/0379-6779(94)90174-0

DO - 10.1016/0379-6779(94)90174-0

M3 - Article

AN - SCOPUS:43949159134

SN - 0379-6779

VL - 65

SP - 131

EP - 140

JO - Synthetic Metals

JF - Synthetic Metals

IS - 2-3

ER -

Recent structural investigations of metallic polymers

Abstract

Keywords

ASJC Scopus subject areas

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