Reduction of acrolein dialkyl, acetals with CrCl2. γy-alkoxy substitued allylic chromium reagents for selective synthesis of erythro-1, 2-diols.

Kazuhiko Takai; Kenji Nitta; Kiitiro Utimoto

doi:10.1016/S0040-4039(00)80732-7

Reduction of acrolein dialkyl, acetals with CrCl₂. γy-alkoxy substitued allylic chromium reagents for selective synthesis of erythro-1, 2-diols.

Kazuhiko Takai, Kenji Nitta, Kiitiro Utimoto

Research output: Contribution to journal › Article › peer-review

55 Citations (Scopus)

Abstract

Treatment of an aldehyde in THF at -30°C with a reagent derived by reduction of acrolein dialkyl acetal with CrCl₂ in the presence of Me₃SiI gave 1,2-erythro-3,4-butene-1,2-diol derivatives selectively.

Original language	English
Pages (from-to)	5263-5266
Number of pages	4
Journal	Tetrahedron Letters
Volume	29
Issue number	41
DOIs	https://doi.org/10.1016/S0040-4039(00)80732-7
Publication status	Published - 1988
Externally published	Yes

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/S0040-4039(00)80732-7

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title = "Reduction of acrolein dialkyl, acetals with CrCl2. γy-alkoxy substitued allylic chromium reagents for selective synthesis of erythro-1, 2-diols.",

abstract = "Treatment of an aldehyde in THF at -30°C with a reagent derived by reduction of acrolein dialkyl acetal with CrCl2 in the presence of Me3SiI gave 1,2-erythro-3,4-butene-1,2-diol derivatives selectively.",

author = "Kazuhiko Takai and Kenji Nitta and Kiitiro Utimoto",

year = "1988",

doi = "10.1016/S0040-4039(00)80732-7",

language = "English",

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journal = "Tetrahedron Letters",

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publisher = "Elsevier Limited",

number = "41",

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T1 - Reduction of acrolein dialkyl, acetals with CrCl2. γy-alkoxy substitued allylic chromium reagents for selective synthesis of erythro-1, 2-diols.

AU - Takai, Kazuhiko

AU - Nitta, Kenji

AU - Utimoto, Kiitiro

PY - 1988

Y1 - 1988

N2 - Treatment of an aldehyde in THF at -30°C with a reagent derived by reduction of acrolein dialkyl acetal with CrCl2 in the presence of Me3SiI gave 1,2-erythro-3,4-butene-1,2-diol derivatives selectively.

AB - Treatment of an aldehyde in THF at -30°C with a reagent derived by reduction of acrolein dialkyl acetal with CrCl2 in the presence of Me3SiI gave 1,2-erythro-3,4-butene-1,2-diol derivatives selectively.

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DO - 10.1016/S0040-4039(00)80732-7

M3 - Article

AN - SCOPUS:0000040266

SN - 0040-4039

VL - 29

SP - 5263

EP - 5266

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 41

ER -

Reduction of acrolein dialkyl, acetals with CrCl₂. γy-alkoxy substitued allylic chromium reagents for selective synthesis of erythro-1, 2-diols.

Abstract

ASJC Scopus subject areas

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