Regio- and stereocontrolled hydrosilylation polyaddition catalyzed by RhI(PPh3)3. Syntheses of polymers containing (E)- or (Z)-alkenylsilane moieties

Atsunori Mori; Eisuke Takahisa; Hiroshi Kajiro; Yasushi Nishihara; Tamejiro Hiyama

doi:10.1021/ma9913360

Regio- and stereocontrolled hydrosilylation polyaddition catalyzed by RhI(PPh₃)₃. Syntheses of polymers containing (E)- or (Z)-alkenylsilane moieties

Atsunori Mori, Eisuke Takahisa, Hiroshi Kajiro, Yasushi Nishihara, Tamejiro Hiyama

Research output: Contribution to journal › Article › peer-review

35 Citations (Scopus)

Abstract

Stereodivergent syntheses of E- and Z-polymers of the alkenylsilane moiety were carried out hand in hand by hydrosilation polyaddition using diethylbenzene and bis(dimethylsily)benzene. Spectroscopic change based on the stereochemistries of polymers was observed.

Original language	English
Pages (from-to)	1115-1116
Number of pages	2
Journal	Macromolecules
Volume	33
Issue number	4
DOIs	https://doi.org/10.1021/ma9913360
Publication status	Published - Jan 1 2000
Externally published	Yes

ASJC Scopus subject areas

Organic Chemistry
Polymers and Plastics
Inorganic Chemistry
Materials Chemistry

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10.1021/ma9913360

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abstract = "Stereodivergent syntheses of E- and Z-polymers of the alkenylsilane moiety were carried out hand in hand by hydrosilation polyaddition using diethylbenzene and bis(dimethylsily)benzene. Spectroscopic change based on the stereochemistries of polymers was observed.",

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AU - Mori, Atsunori

AU - Takahisa, Eisuke

AU - Kajiro, Hiroshi

AU - Nishihara, Yasushi

AU - Hiyama, Tamejiro

PY - 2000/1/1

Y1 - 2000/1/1

N2 - Stereodivergent syntheses of E- and Z-polymers of the alkenylsilane moiety were carried out hand in hand by hydrosilation polyaddition using diethylbenzene and bis(dimethylsily)benzene. Spectroscopic change based on the stereochemistries of polymers was observed.

AB - Stereodivergent syntheses of E- and Z-polymers of the alkenylsilane moiety were carried out hand in hand by hydrosilation polyaddition using diethylbenzene and bis(dimethylsily)benzene. Spectroscopic change based on the stereochemistries of polymers was observed.

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Regio- and stereocontrolled hydrosilylation polyaddition catalyzed by RhI(PPh₃)₃. Syntheses of polymers containing (E)- or (Z)-alkenylsilane moieties

Abstract

ASJC Scopus subject areas

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