Regio- and stereoselective synthesis of multisubstituted vinylsilanes via zirconacycles

Yasushi Nishihara; Daisuke Saito; Kenki Tanemura; Shintaro Noyori; Kentaro Takagi

doi:10.1021/ol901236s

Regio- and stereoselective synthesis of multisubstituted vinylsilanes via zirconacycles

Yasushi Nishihara, Daisuke Saito, Kenki Tanemura, Shintaro Noyori, Kentaro Takagi

Research Institute for Interdisciplinary Science

Research output: Contribution to journal › Article › peer-review

29 Citations (Scopus)

Abstract

Image Persented A series of novel multisubstituted vinylsilanes are prepared regio- and stereoselectively by carbozirconation of various alkynylsilanes through zirconacycles such as zirconacyclopropenes and zirconacyclopentenes and the subsequent transformation of the formed alkenylzirconocene complexes.

Original language	English
Pages (from-to)	3546-3549
Number of pages	4
Journal	Organic Letters
Volume	11
Issue number	16
DOIs	https://doi.org/10.1021/ol901236s
Publication status	Published - Aug 20 2009

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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10.1021/ol901236s

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abstract = "Image Persented A series of novel multisubstituted vinylsilanes are prepared regio- and stereoselectively by carbozirconation of various alkynylsilanes through zirconacycles such as zirconacyclopropenes and zirconacyclopentenes and the subsequent transformation of the formed alkenylzirconocene complexes.",

author = "Yasushi Nishihara and Daisuke Saito and Kenki Tanemura and Shintaro Noyori and Kentaro Takagi",

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T1 - Regio- and stereoselective synthesis of multisubstituted vinylsilanes via zirconacycles

AU - Nishihara, Yasushi

AU - Saito, Daisuke

AU - Tanemura, Kenki

AU - Noyori, Shintaro

AU - Takagi, Kentaro

PY - 2009/8/20

Y1 - 2009/8/20

N2 - Image Persented A series of novel multisubstituted vinylsilanes are prepared regio- and stereoselectively by carbozirconation of various alkynylsilanes through zirconacycles such as zirconacyclopropenes and zirconacyclopentenes and the subsequent transformation of the formed alkenylzirconocene complexes.

AB - Image Persented A series of novel multisubstituted vinylsilanes are prepared regio- and stereoselectively by carbozirconation of various alkynylsilanes through zirconacycles such as zirconacyclopropenes and zirconacyclopentenes and the subsequent transformation of the formed alkenylzirconocene complexes.

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Regio- and stereoselective synthesis of multisubstituted vinylsilanes via zirconacycles

Abstract

ASJC Scopus subject areas

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