Resource recovery of waste incineration fly ash: Synthesis of tobermorite as ion exchanger

Zhidong Yao, Chikashi Tamura, Motohide Matsuda, Michihiro Miyake

    Research output: Contribution to journalArticlepeer-review

    55 Citations (Scopus)

    Abstract

    Tobermorite was synthesized successfully from waste incineration fly ash by hydrothermal treatment in the presence of sodium hydroxide solution. The tobermorite synthesis was examined as a function of reaction temperature, time, and NaOH concentration. The formation of tobermorite was identified in all of the fly ash treated with NaOH at 180 °C, followed by the minor generations of sodalite and cancrinite phases with increasing NaOH concentration and extending reaction time. The NaOH-treated fly ash revealed the uptake behaviors for Cs+ and NH4+, whereas the fly ash untreated with NaOH solution did not show that. The uptake amounts of resulting products were also determined: 0.40 mmol/g for Cs+ and 0.35 mmol/g for NH4+ in the fly ash treated with 2.0 M NaOH at 180 °C for 20 h.

    Original languageEnglish
    Pages (from-to)4437-4442
    Number of pages6
    JournalJournal of Materials Research
    Volume14
    Issue number11
    DOIs
    Publication statusPublished - Nov 1999

    ASJC Scopus subject areas

    • General Materials Science
    • Condensed Matter Physics
    • Mechanics of Materials
    • Mechanical Engineering

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