RhCl(PPh3)3/NaI catalyst system for hydrosilylation of 1-alkynes: Stereodivergent syntheses of E-and Z-alkenylsilanes with heteroatom substituents on silicon

Atsunori Mori; Eisuke Takahisa; Hiroshi Kajiro; Kazunori Hirabayashi; Yasushi Nishihara; Tamejiro Hiyama

doi:10.1246/cl.1998.443

RhCl(PPh₃)₃/NaI catalyst system for hydrosilylation of 1-alkynes: Stereodivergent syntheses of E-and Z-alkenylsilanes with heteroatom substituents on silicon

Atsunori Mori, Eisuke Takahisa, Hiroshi Kajiro, Kazunori Hirabayashi, Yasushi Nishihara, Tamejiro Hiyama

Research output: Contribution to journal › Article › peer-review

63 Citations (Scopus)

Abstract

Both (E)-and (Z)-alkenylsilanes are synthesized by the reaction of hydrosilanes and 1-alkynes catalyzed by RhCl(PPh₃)₃/NaI or RhI(PPh₃)₃ highly selectively.

Original language	English
Pages (from-to)	443-444
Number of pages	2
Journal	Chemistry Letters
Issue number	5
DOIs	https://doi.org/10.1246/cl.1998.443
Publication status	Published - 1998
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)

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10.1246/cl.1998.443

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title = "RhCl(PPh3)3/NaI catalyst system for hydrosilylation of 1-alkynes: Stereodivergent syntheses of E-and Z-alkenylsilanes with heteroatom substituents on silicon",

abstract = "Both (E)-and (Z)-alkenylsilanes are synthesized by the reaction of hydrosilanes and 1-alkynes catalyzed by RhCl(PPh3)3/NaI or RhI(PPh3)3 highly selectively.",

author = "Atsunori Mori and Eisuke Takahisa and Hiroshi Kajiro and Kazunori Hirabayashi and Yasushi Nishihara and Tamejiro Hiyama",

year = "1998",

doi = "10.1246/cl.1998.443",

language = "English",

pages = "443--444",

journal = "Chemistry Letters",

issn = "0366-7022",

publisher = "Chemical Society of Japan",

number = "5",

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T1 - RhCl(PPh3)3/NaI catalyst system for hydrosilylation of 1-alkynes

T2 - Stereodivergent syntheses of E-and Z-alkenylsilanes with heteroatom substituents on silicon

AU - Mori, Atsunori

AU - Takahisa, Eisuke

AU - Kajiro, Hiroshi

AU - Hirabayashi, Kazunori

AU - Nishihara, Yasushi

AU - Hiyama, Tamejiro

PY - 1998

Y1 - 1998

N2 - Both (E)-and (Z)-alkenylsilanes are synthesized by the reaction of hydrosilanes and 1-alkynes catalyzed by RhCl(PPh3)3/NaI or RhI(PPh3)3 highly selectively.

AB - Both (E)-and (Z)-alkenylsilanes are synthesized by the reaction of hydrosilanes and 1-alkynes catalyzed by RhCl(PPh3)3/NaI or RhI(PPh3)3 highly selectively.

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U2 - 10.1246/cl.1998.443

DO - 10.1246/cl.1998.443

M3 - Article

AN - SCOPUS:0032374573

SN - 0366-7022

SP - 443

EP - 444

JO - Chemistry Letters

JF - Chemistry Letters

IS - 5

ER -

RhCl(PPh₃)₃/NaI catalyst system for hydrosilylation of 1-alkynes: Stereodivergent syntheses of E-and Z-alkenylsilanes with heteroatom substituents on silicon

Abstract

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