Rhenium-catalysed dehydrogenative borylation of primary and secondary C(sp3)-H bonds adjacent to a nitrogen atom

Masahito Murai; Tetsuya Omura; Yoichiro Kuninobu; Kazuhiko Takai

doi:10.1039/c4cc09508a

Rhenium-catalysed dehydrogenative borylation of primary and secondary C(sp³)-H bonds adjacent to a nitrogen atom

Masahito Murai, Tetsuya Omura, Yoichiro Kuninobu, Kazuhiko Takai

Research output: Contribution to journal › Article › peer-review

29 Citations (Scopus)

Abstract

Rhenium-catalysed C(sp³)-H bond borylation in the absence of any oxidant, hydrogen acceptor, or external ligand, with the generation of H₂ as the sole byproduct is described. The transformation, which represents a rare example of rhenium-catalysed C(sp³)-H bond functionalisation, features high atom efficiency and simple reaction conditions. This journal is

Original language	English
Pages (from-to)	4583-4586
Number of pages	4
Journal	Chemical Communications
Volume	51
Issue number	22
DOIs	https://doi.org/10.1039/c4cc09508a
Publication status	Published - Mar 18 2015

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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AU - Kuninobu, Yoichiro

AU - Takai, Kazuhiko

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Rhenium-catalysed dehydrogenative borylation of primary and secondary C(sp³)-H bonds adjacent to a nitrogen atom

Abstract

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