Rhenium-catalyzed ortho-alkylation of phenols

Yoichiro Kuninobu; Masaki Yamamoto; Mitsumi Nishi; Tomoyuki Yamamoto; Takashi Matsuki; Masahito Murai; Kazuhiko Takai

doi:10.1002/0471264229.os094.20

Rhenium-catalyzed ortho-alkylation of phenols

Yoichiro Kuninobu
, Masaki Yamamoto
, Mitsumi Nishi
, Tomoyuki Yamamoto
, Takashi Matsuki
, Masahito Murai
, Kazuhiko Takai

School of Engineering

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

A procedure yielding pure 2-(1-methylnonyl)phenol (1) as a colorless oil is presented. An oven-dried Schlenk flask with a Teflon-coated magnetic stir bar and a reflux condenser with a three-way stopcock is primarily used as paraphernalia. A discussion on ortho-monoalkylated phenol derivatives as important bioactive compounds and functional materials concludes the chapter.

Original language	English
Journal	Organic Syntheses
Volume	94
DOIs	https://doi.org/10.1002/0471264229.os094.20
Publication status	Published - Jun 20 2018

Keywords

2-(1-methylnonyl)phenol
Dirhenium decacarbonyl
Friedel-Crafts alkylation
Kugelrohr distillation
Monoalkylated phenols

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry

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10.1002/0471264229.os094.20

Cite this

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title = "Rhenium-catalyzed ortho-alkylation of phenols",

abstract = "A procedure yielding pure 2-(1-methylnonyl)phenol (1) as a colorless oil is presented. An oven-dried Schlenk flask with a Teflon-coated magnetic stir bar and a reflux condenser with a three-way stopcock is primarily used as paraphernalia. A discussion on ortho-monoalkylated phenol derivatives as important bioactive compounds and functional materials concludes the chapter.",

keywords = "2-(1-methylnonyl)phenol, Dirhenium decacarbonyl, Friedel-Crafts alkylation, Kugelrohr distillation, Monoalkylated phenols",

author = "Yoichiro Kuninobu and Masaki Yamamoto and Mitsumi Nishi and Tomoyuki Yamamoto and Takashi Matsuki and Masahito Murai and Kazuhiko Takai",

year = "2018",

month = jun,

day = "20",

doi = "10.1002/0471264229.os094.20",

language = "English",

volume = "94",

journal = "Organic Syntheses",

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T1 - Rhenium-catalyzed ortho-alkylation of phenols

AU - Kuninobu, Yoichiro

AU - Yamamoto, Masaki

AU - Nishi, Mitsumi

AU - Yamamoto, Tomoyuki

AU - Matsuki, Takashi

AU - Murai, Masahito

AU - Takai, Kazuhiko

PY - 2018/6/20

Y1 - 2018/6/20

N2 - A procedure yielding pure 2-(1-methylnonyl)phenol (1) as a colorless oil is presented. An oven-dried Schlenk flask with a Teflon-coated magnetic stir bar and a reflux condenser with a three-way stopcock is primarily used as paraphernalia. A discussion on ortho-monoalkylated phenol derivatives as important bioactive compounds and functional materials concludes the chapter.

AB - A procedure yielding pure 2-(1-methylnonyl)phenol (1) as a colorless oil is presented. An oven-dried Schlenk flask with a Teflon-coated magnetic stir bar and a reflux condenser with a three-way stopcock is primarily used as paraphernalia. A discussion on ortho-monoalkylated phenol derivatives as important bioactive compounds and functional materials concludes the chapter.

KW - 2-(1-methylnonyl)phenol

KW - Dirhenium decacarbonyl

KW - Friedel-Crafts alkylation

KW - Kugelrohr distillation

KW - Monoalkylated phenols

UR - https://www.scopus.com/pages/publications/85054817547

UR - https://www.scopus.com/pages/publications/85054817547#tab=citedBy

U2 - 10.1002/0471264229.os094.20

DO - 10.1002/0471264229.os094.20

M3 - Article

AN - SCOPUS:85054817547

SN - 0078-6209

VL - 94

JO - Organic Syntheses

JF - Organic Syntheses

ER -

Rhenium-catalyzed ortho-alkylation of phenols

Abstract

Keywords

ASJC Scopus subject areas

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