Rhenium-catalyzed regioselective alkylation of phenols

Yoichiro Kuninobu; Takashi Matsuki; Kazuhiko Takai

doi:10.1021/ja904360k

Rhenium-catalyzed regioselective alkylation of phenols

Yoichiro Kuninobu, Takashi Matsuki, Kazuhiko Takai

Research output: Contribution to journal › Article › peer-review

83 Citations (Scopus)

Abstract

(Chemical Equation Presented) Treatment of phenol derivatives with terminal alkenes in the presence of a catalytic amount of a rhenium complex, Re ₂(CO)₁₀, gave monoalkylated phenol derivatives in good to excellent yields. This reaction proceeds at the ortho- or para-position of phenols regioselectively.

Original language	English
Pages (from-to)	9914-9915
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	131
Issue number	29
DOIs	https://doi.org/10.1021/ja904360k
Publication status	Published - Jul 29 2009

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

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10.1021/ja904360k

Cite this

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abstract = "(Chemical Equation Presented) Treatment of phenol derivatives with terminal alkenes in the presence of a catalytic amount of a rhenium complex, Re 2(CO)10, gave monoalkylated phenol derivatives in good to excellent yields. This reaction proceeds at the ortho- or para-position of phenols regioselectively.",

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AU - Matsuki, Takashi

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N2 - (Chemical Equation Presented) Treatment of phenol derivatives with terminal alkenes in the presence of a catalytic amount of a rhenium complex, Re 2(CO)10, gave monoalkylated phenol derivatives in good to excellent yields. This reaction proceeds at the ortho- or para-position of phenols regioselectively.

AB - (Chemical Equation Presented) Treatment of phenol derivatives with terminal alkenes in the presence of a catalytic amount of a rhenium complex, Re 2(CO)10, gave monoalkylated phenol derivatives in good to excellent yields. This reaction proceeds at the ortho- or para-position of phenols regioselectively.

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Rhenium-catalyzed regioselective alkylation of phenols

Abstract

ASJC Scopus subject areas

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