Rhodium-catalyzed arylative cyclization reaction of diynes with arylboronic acids

Tomoya Miura; Motoshi Yamauchi; Masahiro Murakami

doi:10.1055/s-2007-984879

Rhodium-catalyzed arylative cyclization reaction of diynes with arylboronic acids

Tomoya Miura, Motoshi Yamauchi, Masahiro Murakami

Research output: Contribution to journal › Article › peer-review

21 Citations (Scopus)

Abstract

Diynes having malonate-based tethers react with arylboronic acids in the presence of a rhodium(I) catalyst to give 1,2-dialkylidenecycloalkanes. The regioselectivity of the initial carborhodation depends on the sterics and the directing nature of the alkyne substituents.

Original language	English
Pages (from-to)	2029-2032
Number of pages	4
Journal	Synlett
Issue number	13
DOIs	https://doi.org/10.1055/s-2007-984879
Publication status	Published - Aug 13 2007
Externally published	Yes

Keywords

Addition reactions
Arylboronic acids
Cyclizations
Diynes
Rhodium

ASJC Scopus subject areas

Organic Chemistry

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10.1055/s-2007-984879

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title = "Rhodium-catalyzed arylative cyclization reaction of diynes with arylboronic acids",

abstract = "Diynes having malonate-based tethers react with arylboronic acids in the presence of a rhodium(I) catalyst to give 1,2-dialkylidenecycloalkanes. The regioselectivity of the initial carborhodation depends on the sterics and the directing nature of the alkyne substituents.",

keywords = "Addition reactions, Arylboronic acids, Cyclizations, Diynes, Rhodium",

author = "Tomoya Miura and Motoshi Yamauchi and Masahiro Murakami",

note = "Funding Information: The research was supported by the National Science Council of the Republic of China under the grant NSC 92-2213-E-014-015-.",

year = "2007",

month = aug,

day = "13",

doi = "10.1055/s-2007-984879",

language = "English",

pages = "2029--2032",

journal = "Synlett",

issn = "0936-5214",

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TY - JOUR

T1 - Rhodium-catalyzed arylative cyclization reaction of diynes with arylboronic acids

AU - Miura, Tomoya

AU - Yamauchi, Motoshi

AU - Murakami, Masahiro

N1 - Funding Information: The research was supported by the National Science Council of the Republic of China under the grant NSC 92-2213-E-014-015-.

PY - 2007/8/13

Y1 - 2007/8/13

N2 - Diynes having malonate-based tethers react with arylboronic acids in the presence of a rhodium(I) catalyst to give 1,2-dialkylidenecycloalkanes. The regioselectivity of the initial carborhodation depends on the sterics and the directing nature of the alkyne substituents.

AB - Diynes having malonate-based tethers react with arylboronic acids in the presence of a rhodium(I) catalyst to give 1,2-dialkylidenecycloalkanes. The regioselectivity of the initial carborhodation depends on the sterics and the directing nature of the alkyne substituents.

KW - Addition reactions

KW - Arylboronic acids

KW - Cyclizations

KW - Diynes

KW - Rhodium

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UR - http://www.scopus.com/inward/citedby.url?scp=34548152096&partnerID=8YFLogxK

U2 - 10.1055/s-2007-984879

DO - 10.1055/s-2007-984879

M3 - Article

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SN - 0936-5214

SP - 2029

EP - 2032

JO - Synlett

JF - Synlett

IS - 13

ER -

Rhodium-catalyzed arylative cyclization reaction of diynes with arylboronic acids

Abstract

Keywords

ASJC Scopus subject areas

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