Rhodium-catalyzed carbene-transfer reactions via thienylcarbene complexes generated from thiocarbamoyl-ene-yne compounds

Asuka Tsuneishi; Kazuhiro Okamoto; Yuji Ikeda; Masahito Murai; Koji Miki; Kouichi Ohe

doi:10.1055/s-0030-1259559

Rhodium-catalyzed carbene-transfer reactions via thienylcarbene complexes generated from thiocarbamoyl-ene-yne compounds

Asuka Tsuneishi, Kazuhiro Okamoto, Yuji Ikeda, Masahito Murai, Koji Miki, Kouichi Ohe

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

Catalytic thienylcarbene-transfer reactions have been developed. The rhodium-catalyzed reaction of alkenes, furans, and thiophenes with a thiocarbamoyl-ene-yne compound as a carbene source gave the cyclopropanation products or ring-opened products of heterocycles. These processes provide efficient synthetic methods for thiophene-containing complex molecules.

Original language	English
Article number	U11510ST
Pages (from-to)	655-658
Number of pages	4
Journal	Synlett
Issue number	5
DOIs	https://doi.org/10.1055/s-0030-1259559
Publication status	Published - 2011
Externally published	Yes

Keywords

carbene complex
cyclopropanation
rhodium
ring-opening reaction
thiocarbamoyl-ene-yne

ASJC Scopus subject areas

Organic Chemistry

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year = "2011",

doi = "10.1055/s-0030-1259559",

language = "English",

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T1 - Rhodium-catalyzed carbene-transfer reactions via thienylcarbene complexes generated from thiocarbamoyl-ene-yne compounds

AU - Tsuneishi, Asuka

AU - Okamoto, Kazuhiro

AU - Ikeda, Yuji

AU - Murai, Masahito

AU - Miki, Koji

AU - Ohe, Kouichi

PY - 2011

Y1 - 2011

N2 - Catalytic thienylcarbene-transfer reactions have been developed. The rhodium-catalyzed reaction of alkenes, furans, and thiophenes with a thiocarbamoyl-ene-yne compound as a carbene source gave the cyclopropanation products or ring-opened products of heterocycles. These processes provide efficient synthetic methods for thiophene-containing complex molecules.

AB - Catalytic thienylcarbene-transfer reactions have been developed. The rhodium-catalyzed reaction of alkenes, furans, and thiophenes with a thiocarbamoyl-ene-yne compound as a carbene source gave the cyclopropanation products or ring-opened products of heterocycles. These processes provide efficient synthetic methods for thiophene-containing complex molecules.

KW - carbene complex

KW - cyclopropanation

KW - rhodium

KW - ring-opening reaction

KW - thiocarbamoyl-ene-yne

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ER -

Rhodium-catalyzed carbene-transfer reactions via thienylcarbene complexes generated from thiocarbamoyl-ene-yne compounds

Abstract

Keywords

ASJC Scopus subject areas

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