Rhodium-catalyzed synthesis of silafluorene derivatives via cleavage of silicon-hydrogen and carbon-hydrogen bonds

Tomonari Ureshino; Takuya Yoshida; Yoichiro Kuninobu; Kazuhiko Takai

doi:10.1021/ja107698p

Rhodium-catalyzed synthesis of silafluorene derivatives via cleavage of silicon-hydrogen and carbon-hydrogen bonds

Tomonari Ureshino, Takuya Yoshida, Yoichiro Kuninobu, Kazuhiko Takai

School of Engineering

Research output: Contribution to journal › Article › peer-review

196 Citations (Scopus)

Abstract

The rhodium-catalyzed synthesis of silafluorenes from biphenylhydrosilanes is described. This highly efficient reaction proceeds via both Si-H and C-H bond activation, producing only H₂ as a side product. Using this method, a ladder-type bis-silicon-bridged p-terphenyl could also be synthesized.

Original language	English
Pages (from-to)	14324-14326
Number of pages	3
Journal	Journal of the American Chemical Society
Volume	132
Issue number	41
DOIs	https://doi.org/10.1021/ja107698p
Publication status	Published - Oct 20 2010

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

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10.1021/ja107698p

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abstract = "The rhodium-catalyzed synthesis of silafluorenes from biphenylhydrosilanes is described. This highly efficient reaction proceeds via both Si-H and C-H bond activation, producing only H2 as a side product. Using this method, a ladder-type bis-silicon-bridged p-terphenyl could also be synthesized.",

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AU - Ureshino, Tomonari

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AU - Kuninobu, Yoichiro

AU - Takai, Kazuhiko

PY - 2010/10/20

Y1 - 2010/10/20

N2 - The rhodium-catalyzed synthesis of silafluorenes from biphenylhydrosilanes is described. This highly efficient reaction proceeds via both Si-H and C-H bond activation, producing only H2 as a side product. Using this method, a ladder-type bis-silicon-bridged p-terphenyl could also be synthesized.

AB - The rhodium-catalyzed synthesis of silafluorenes from biphenylhydrosilanes is described. This highly efficient reaction proceeds via both Si-H and C-H bond activation, producing only H2 as a side product. Using this method, a ladder-type bis-silicon-bridged p-terphenyl could also be synthesized.

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Rhodium-catalyzed synthesis of silafluorene derivatives via cleavage of silicon-hydrogen and carbon-hydrogen bonds

Abstract

ASJC Scopus subject areas

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