Ruthenium-catalyzed ring-closing reaction of α,ω-bis(vinylsilyl) compounds via a silyl transfer mechanism

Takaya Mise; Yutaka Takaguchi; Takeshi Umemiya; Shoichi Shimizu; Yasuo Wakatsuki

doi:10.1039/a800293b

Ruthenium-catalyzed ring-closing reaction of α,ω-bis(vinylsilyl) compounds via a silyl transfer mechanism

Takaya Mise, Yutaka Takaguchi, Takeshi Umemiya, Shoichi Shimizu, Yasuo Wakatsuki

Research output: Contribution to journal › Article › peer-review

48 Citations (Scopus)

Abstract

Compounds having a vinyldimethylsilyl group at both terminals have been successfully cyclized by ruthenium hydride catalysts to give selectively disilacycles of various ring sizes via a metathetical reaction, i.e. ethene elimination from the two terminal vinyl groups, not involving metallocarbene-metallacyclobutane type intermediates.

Original language	English
Pages (from-to)	699-700
Number of pages	2
Journal	Chemical Communications
Issue number	6
DOIs	https://doi.org/10.1039/a800293b
Publication status	Published - Mar 21 1998
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/a800293b

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abstract = "Compounds having a vinyldimethylsilyl group at both terminals have been successfully cyclized by ruthenium hydride catalysts to give selectively disilacycles of various ring sizes via a metathetical reaction, i.e. ethene elimination from the two terminal vinyl groups, not involving metallocarbene-metallacyclobutane type intermediates.",

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AU - Mise, Takaya

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AU - Umemiya, Takeshi

AU - Shimizu, Shoichi

AU - Wakatsuki, Yasuo

PY - 1998/3/21

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N2 - Compounds having a vinyldimethylsilyl group at both terminals have been successfully cyclized by ruthenium hydride catalysts to give selectively disilacycles of various ring sizes via a metathetical reaction, i.e. ethene elimination from the two terminal vinyl groups, not involving metallocarbene-metallacyclobutane type intermediates.

AB - Compounds having a vinyldimethylsilyl group at both terminals have been successfully cyclized by ruthenium hydride catalysts to give selectively disilacycles of various ring sizes via a metathetical reaction, i.e. ethene elimination from the two terminal vinyl groups, not involving metallocarbene-metallacyclobutane type intermediates.

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Ruthenium-catalyzed ring-closing reaction of α,ω-bis(vinylsilyl) compounds via a silyl transfer mechanism

Abstract

ASJC Scopus subject areas

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