TY - JOUR
T1 - Ruthenium(II) complex containing a new hybrid bidentate phosphine-thioether ligand
T2 - [(p-cymene)RuCl-(Me2PCH2CH2SMe)][BPh 4].0.5CH2Cl2
AU - Suzuki, Takayoshi
AU - Taguchi, Norihiko
AU - Kashiwabara, Kazuo
PY - 1996/12/15
Y1 - 1996/12/15
N2 - In the title compound, chloro(η 6-p-cymene)[1-(dimethylphosphino-P)-2-(methylthio-S)ethane] ruthenium(II) tetraphenylborate hemidichloromethane solvate, [RuCl-(C10H14)(C5H13PS)][B(C 6H5)4].0.5CH2Cl2, the hybrid Me2PCH2CH2SMe ligand is bidentate (κ2P,S), forming a five-membered chelate ring. The complex cation has two chiral centres, i.e. on the Ru and S atoms, and the relative configuration is R *(Ru)S*(S).
AB - In the title compound, chloro(η 6-p-cymene)[1-(dimethylphosphino-P)-2-(methylthio-S)ethane] ruthenium(II) tetraphenylborate hemidichloromethane solvate, [RuCl-(C10H14)(C5H13PS)][B(C 6H5)4].0.5CH2Cl2, the hybrid Me2PCH2CH2SMe ligand is bidentate (κ2P,S), forming a five-membered chelate ring. The complex cation has two chiral centres, i.e. on the Ru and S atoms, and the relative configuration is R *(Ru)S*(S).
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U2 - 10.1107/S010827019601030X
DO - 10.1107/S010827019601030X
M3 - Article
AN - SCOPUS:0030413872
SN - 0108-2701
VL - 52
SP - 2982
EP - 2984
JO - Acta Crystallographica Section C: Crystal Structure Communications
JF - Acta Crystallographica Section C: Crystal Structure Communications
IS - 12
ER -