Site-selective introduction of an enamido group at the C(3)-Position of Indoles

Tomoya Miura; Qiang Zhao; Yuuta Funakoshi; Masahiro Murakami

doi:10.3987/COM-15-13261

Site-selective introduction of an enamido group at the C(3)-Position of Indoles

Tomoya Miura, Qiang Zhao, Yuuta Funakoshi, Masahiro Murakami

Research output: Contribution to journal › Article › peer-review

18 Citations (Scopus)

Abstract

An enamido group is introduced site-selectively at the C(3)-position of indoles by the rhodium(II)-catalyzed reaction with N-sulfonyl-1,2,3-triazoles. Formally, an α-imino rhodium carbene complex is inserted into the C(3)-H bond of an indole.

Original language	English
Pages (from-to)	1579-1584
Number of pages	6
Journal	Heterocycles
Volume	91
Issue number	8
DOIs	https://doi.org/10.3987/COM-15-13261
Publication status	Published - 2015
Externally published	Yes

ASJC Scopus subject areas

Analytical Chemistry
Pharmacology
Organic Chemistry

Access to Document

10.3987/COM-15-13261

Cite this

@article{08952874775d4f45bdc03696711a1780,

title = "Site-selective introduction of an enamido group at the C(3)-Position of Indoles",

abstract = "An enamido group is introduced site-selectively at the C(3)-position of indoles by the rhodium(II)-catalyzed reaction with N-sulfonyl-1,2,3-triazoles. Formally, an α-imino rhodium carbene complex is inserted into the C(3)-H bond of an indole.",

author = "Tomoya Miura and Qiang Zhao and Yuuta Funakoshi and Masahiro Murakami",

note = "Publisher Copyright: {\textcopyright} 2015 The Japan Institute of Heterocyclic Chemistry Received.",

year = "2015",

doi = "10.3987/COM-15-13261",

language = "English",

volume = "91",

pages = "1579--1584",

journal = "Heterocycles",

issn = "0385-5414",

publisher = "Japan Institute of Heterocyclic Chemistry",

number = "8",

}

TY - JOUR

T1 - Site-selective introduction of an enamido group at the C(3)-Position of Indoles

AU - Miura, Tomoya

AU - Zhao, Qiang

AU - Funakoshi, Yuuta

AU - Murakami, Masahiro

PY - 2015

Y1 - 2015

N2 - An enamido group is introduced site-selectively at the C(3)-position of indoles by the rhodium(II)-catalyzed reaction with N-sulfonyl-1,2,3-triazoles. Formally, an α-imino rhodium carbene complex is inserted into the C(3)-H bond of an indole.

AB - An enamido group is introduced site-selectively at the C(3)-position of indoles by the rhodium(II)-catalyzed reaction with N-sulfonyl-1,2,3-triazoles. Formally, an α-imino rhodium carbene complex is inserted into the C(3)-H bond of an indole.

UR - http://www.scopus.com/inward/record.url?scp=84941762431&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84941762431&partnerID=8YFLogxK

U2 - 10.3987/COM-15-13261

DO - 10.3987/COM-15-13261

M3 - Article

AN - SCOPUS:84941762431

SN - 0385-5414

VL - 91

SP - 1579

EP - 1584

JO - Heterocycles

JF - Heterocycles

IS - 8

ER -

Site-selective introduction of an enamido group at the C(3)-Position of Indoles

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this