Stereodivergent hydrosilylation of 1-alkynes catalyzed by RhI (PPh3)3 leading to (E)- and (Z)-alkenylsilanes and the application to polymer synthesis

Atsunori Mori; Eisuke Takahisa; Hiroshi Kajiro; Yasushi Nishihara; Tamejiro Hiyama

doi:10.1016/S0277-5387(99)00409-X

Stereodivergent hydrosilylation of 1-alkynes catalyzed by RhI (PPh₃)₃ leading to (E)- and (Z)-alkenylsilanes and the application to polymer synthesis

Atsunori Mori, Eisuke Takahisa, Hiroshi Kajiro, Yasushi Nishihara, Tamejiro Hiyama

Research output: Contribution to journal › Article › peer-review

27 Citations (Scopus)

Abstract

Hydrosilylation of 1-alkynes catalyzed by RhI(PPh₃)₃ gives (E)- and (Z)-alkenylsilanes in a stereodivergent manner by switching the reaction conditions and the order of the addition of the reagents. The reaction is also applied to the synthesis of silicon-containing polymers with (E) and (Z) main-chain structures via polyaddition. (C) 2000 Elsevier Science Ltd All rights reserved.

Original language	English
Pages (from-to)	567-568
Number of pages	2
Journal	Polyhedron
Volume	19
Issue number	5
DOIs	https://doi.org/10.1016/S0277-5387(99)00409-X
Publication status	Published - Mar 15 2000
Externally published	Yes

Keywords

Alkenylsilanes
Hydrosilylation
Polyaddition
RhI(PPh)
Stereodivergent

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1016/S0277-5387(99)00409-X

Cite this

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title = "Stereodivergent hydrosilylation of 1-alkynes catalyzed by RhI (PPh3)3 leading to (E)- and (Z)-alkenylsilanes and the application to polymer synthesis",

abstract = "Hydrosilylation of 1-alkynes catalyzed by RhI(PPh3)3 gives (E)- and (Z)-alkenylsilanes in a stereodivergent manner by switching the reaction conditions and the order of the addition of the reagents. The reaction is also applied to the synthesis of silicon-containing polymers with (E) and (Z) main-chain structures via polyaddition. (C) 2000 Elsevier Science Ltd All rights reserved.",

keywords = "Alkenylsilanes, Hydrosilylation, Polyaddition, RhI(PPh), Stereodivergent",

author = "Atsunori Mori and Eisuke Takahisa and Hiroshi Kajiro and Yasushi Nishihara and Tamejiro Hiyama",

year = "2000",

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T1 - Stereodivergent hydrosilylation of 1-alkynes catalyzed by RhI (PPh3)3 leading to (E)- and (Z)-alkenylsilanes and the application to polymer synthesis

AU - Mori, Atsunori

AU - Takahisa, Eisuke

AU - Kajiro, Hiroshi

AU - Nishihara, Yasushi

AU - Hiyama, Tamejiro

PY - 2000/3/15

Y1 - 2000/3/15

N2 - Hydrosilylation of 1-alkynes catalyzed by RhI(PPh3)3 gives (E)- and (Z)-alkenylsilanes in a stereodivergent manner by switching the reaction conditions and the order of the addition of the reagents. The reaction is also applied to the synthesis of silicon-containing polymers with (E) and (Z) main-chain structures via polyaddition. (C) 2000 Elsevier Science Ltd All rights reserved.

AB - Hydrosilylation of 1-alkynes catalyzed by RhI(PPh3)3 gives (E)- and (Z)-alkenylsilanes in a stereodivergent manner by switching the reaction conditions and the order of the addition of the reagents. The reaction is also applied to the synthesis of silicon-containing polymers with (E) and (Z) main-chain structures via polyaddition. (C) 2000 Elsevier Science Ltd All rights reserved.

KW - Alkenylsilanes

KW - Hydrosilylation

KW - Polyaddition

KW - RhI(PPh)

KW - Stereodivergent

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JF - Polyhedron

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