Stereoselective synthesis of the C79-C97 fragment of symbiodinolide

Hiroyoshi Takamura; Takayuki Fujiwara; Isao Kadota; Daisuke Uemura

doi:10.3762/bjoc.9.228

Stereoselective synthesis of the C79-C97 fragment of symbiodinolide

Hiroyoshi Takamura, Takayuki Fujiwara, Isao Kadota, Daisuke Uemura

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

Symbiodinolide is a polyol marine natural product with a molecular weight of 2860. Herein, a streamlined synthesis of the C79-C97 fragment of symbiodinolide is described. In the synthetic route, a spiroacetalization, a Julia-Kocienski olefination, and a Sharpless asymmetric dihydroxylation were utilized as the key transformations.

Original language	English
Pages (from-to)	1931-1935
Number of pages	5
Journal	Beilstein Journal of Organic Chemistry
Volume	9
DOIs	https://doi.org/10.3762/bjoc.9.228
Publication status	Published - Sept 25 2013

Keywords

Julia-Kocienski olefination
Polyol marine natural product
Sharpless asymmetric dihydroxylation
Spiroacetalization
Symbiodinolide

ASJC Scopus subject areas

Organic Chemistry

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.3762/bjoc.9.228

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abstract = "Symbiodinolide is a polyol marine natural product with a molecular weight of 2860. Herein, a streamlined synthesis of the C79-C97 fragment of symbiodinolide is described. In the synthetic route, a spiroacetalization, a Julia-Kocienski olefination, and a Sharpless asymmetric dihydroxylation were utilized as the key transformations.",

keywords = "Julia-Kocienski olefination, Polyol marine natural product, Sharpless asymmetric dihydroxylation, Spiroacetalization, Symbiodinolide",

author = "Hiroyoshi Takamura and Takayuki Fujiwara and Isao Kadota and Daisuke Uemura",

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language = "English",

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T1 - Stereoselective synthesis of the C79-C97 fragment of symbiodinolide

AU - Takamura, Hiroyoshi

AU - Fujiwara, Takayuki

AU - Kadota, Isao

AU - Uemura, Daisuke

PY - 2013/9/25

Y1 - 2013/9/25

N2 - Symbiodinolide is a polyol marine natural product with a molecular weight of 2860. Herein, a streamlined synthesis of the C79-C97 fragment of symbiodinolide is described. In the synthetic route, a spiroacetalization, a Julia-Kocienski olefination, and a Sharpless asymmetric dihydroxylation were utilized as the key transformations.

AB - Symbiodinolide is a polyol marine natural product with a molecular weight of 2860. Herein, a streamlined synthesis of the C79-C97 fragment of symbiodinolide is described. In the synthetic route, a spiroacetalization, a Julia-Kocienski olefination, and a Sharpless asymmetric dihydroxylation were utilized as the key transformations.

KW - Julia-Kocienski olefination

KW - Polyol marine natural product

KW - Sharpless asymmetric dihydroxylation

KW - Spiroacetalization

KW - Symbiodinolide

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JO - Beilstein Journal of Organic Chemistry

JF - Beilstein Journal of Organic Chemistry

ER -

Stereoselective synthesis of the C79-C97 fragment of symbiodinolide

Abstract

Keywords

ASJC Scopus subject areas

UN SDGs

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