Structural change in a series of protonated layered perovskite compounds, HLnTiO4 (Ln=La, Nd and Y)

Shunsuke Nishimoto; Motohide Matsuda; Stefanus Harjo; Akinori Hoshikawa; Takashi Kamiyama; Toru Ishigaki; Michihiro Miyake

doi:10.1016/j.jssc.2006.03.015

Structural change in a series of protonated layered perovskite compounds, HLnTiO₄ (Ln=La, Nd and Y)

Shunsuke Nishimoto, Motohide Matsuda, Stefanus Harjo, Akinori Hoshikawa, Takashi Kamiyama, Toru Ishigaki, Michihiro Miyake

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

Abstract

A deuterated n=1 Ruddlesden-Popper compound, DLnTiO₄ (HLnTiO₄, Ln=La, Nd and Y), was prepared by an ion-exchange reaction of Na⁺ ions in NaLnTiO₄ with D⁺ ions, and its structure was analyzed by Rietveld method using powder neutron diffraction data. The structure analyses showed that DLaTiO₄ and DNdTiO₄ crystallized in the space group P 4 / nmm with a=3.7232(1) and c=12.3088(1) Å, and a=3.7039(1) and c=12.0883(1) Å, respectively. On the other hand, DYTiO₄ crystallized in the space group P 2₁ / c with a=11.460(1), b=5.2920(4), c=5.3628(5) Å and β=90.441(9)°. The loaded protons were found to statistically occupy the sites around an apical oxygen of TiO₆ octahedron in the interlayer of these compounds, rather than Na atom sites in NaLnTiO₄.

Original language	English
Pages (from-to)	1892-1897
Number of pages	6
Journal	Journal of Solid State Chemistry
Volume	179
Issue number	6
DOIs	https://doi.org/10.1016/j.jssc.2006.03.015
Publication status	Published - Jun 2006

Keywords

Crystal structure
Ion-exchange
Layered perovskite
Neutron diffraction
Ruddlesden-Popper phase

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Ceramics and Composites
Condensed Matter Physics
Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1016/j.jssc.2006.03.015

Cite this

@article{288a79e671c1476aaf349bc5f2866a99,

title = "Structural change in a series of protonated layered perovskite compounds, HLnTiO4 (Ln=La, Nd and Y)",

abstract = "A deuterated n=1 Ruddlesden-Popper compound, DLnTiO4 (HLnTiO4, Ln=La, Nd and Y), was prepared by an ion-exchange reaction of Na+ ions in NaLnTiO4 with D+ ions, and its structure was analyzed by Rietveld method using powder neutron diffraction data. The structure analyses showed that DLaTiO4 and DNdTiO4 crystallized in the space group P 4 / nmm with a=3.7232(1) and c=12.3088(1) {\AA}, and a=3.7039(1) and c=12.0883(1) {\AA}, respectively. On the other hand, DYTiO4 crystallized in the space group P 21 / c with a=11.460(1), b=5.2920(4), c=5.3628(5) {\AA} and β=90.441(9)°. The loaded protons were found to statistically occupy the sites around an apical oxygen of TiO6 octahedron in the interlayer of these compounds, rather than Na atom sites in NaLnTiO4.",

keywords = "Crystal structure, Ion-exchange, Layered perovskite, Neutron diffraction, Ruddlesden-Popper phase",

author = "Shunsuke Nishimoto and Motohide Matsuda and Stefanus Harjo and Akinori Hoshikawa and Takashi Kamiyama and Toru Ishigaki and Michihiro Miyake",

note = "Funding Information: We thank Dr. F. Izumi of National Institute for Materials Science in Japan for kindly supplying RIETAN-TN program. This work was partly supported by The Okayama University 21st Century COE Program “Strategic Solid Waste Management of sustainable Society”.",

year = "2006",

month = jun,

doi = "10.1016/j.jssc.2006.03.015",

language = "English",

volume = "179",

pages = "1892--1897",

journal = "Journal of Solid State Chemistry",

issn = "0022-4596",

publisher = "Academic Press Inc.",

number = "6",

}

TY - JOUR

T1 - Structural change in a series of protonated layered perovskite compounds, HLnTiO4 (Ln=La, Nd and Y)

AU - Nishimoto, Shunsuke

AU - Matsuda, Motohide

AU - Harjo, Stefanus

AU - Hoshikawa, Akinori

AU - Kamiyama, Takashi

AU - Ishigaki, Toru

AU - Miyake, Michihiro

N1 - Funding Information: We thank Dr. F. Izumi of National Institute for Materials Science in Japan for kindly supplying RIETAN-TN program. This work was partly supported by The Okayama University 21st Century COE Program “Strategic Solid Waste Management of sustainable Society”.

PY - 2006/6

Y1 - 2006/6

N2 - A deuterated n=1 Ruddlesden-Popper compound, DLnTiO4 (HLnTiO4, Ln=La, Nd and Y), was prepared by an ion-exchange reaction of Na+ ions in NaLnTiO4 with D+ ions, and its structure was analyzed by Rietveld method using powder neutron diffraction data. The structure analyses showed that DLaTiO4 and DNdTiO4 crystallized in the space group P 4 / nmm with a=3.7232(1) and c=12.3088(1) Å, and a=3.7039(1) and c=12.0883(1) Å, respectively. On the other hand, DYTiO4 crystallized in the space group P 21 / c with a=11.460(1), b=5.2920(4), c=5.3628(5) Å and β=90.441(9)°. The loaded protons were found to statistically occupy the sites around an apical oxygen of TiO6 octahedron in the interlayer of these compounds, rather than Na atom sites in NaLnTiO4.

AB - A deuterated n=1 Ruddlesden-Popper compound, DLnTiO4 (HLnTiO4, Ln=La, Nd and Y), was prepared by an ion-exchange reaction of Na+ ions in NaLnTiO4 with D+ ions, and its structure was analyzed by Rietveld method using powder neutron diffraction data. The structure analyses showed that DLaTiO4 and DNdTiO4 crystallized in the space group P 4 / nmm with a=3.7232(1) and c=12.3088(1) Å, and a=3.7039(1) and c=12.0883(1) Å, respectively. On the other hand, DYTiO4 crystallized in the space group P 21 / c with a=11.460(1), b=5.2920(4), c=5.3628(5) Å and β=90.441(9)°. The loaded protons were found to statistically occupy the sites around an apical oxygen of TiO6 octahedron in the interlayer of these compounds, rather than Na atom sites in NaLnTiO4.

KW - Crystal structure

KW - Ion-exchange

KW - Layered perovskite

KW - Neutron diffraction

KW - Ruddlesden-Popper phase

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AN - SCOPUS:33747098902

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EP - 1897

JO - Journal of Solid State Chemistry

JF - Journal of Solid State Chemistry

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