Structural observation of amorphous (Ti0.676Zr0.324)D0.31 by neutron and X-ray diffraction

K. Itoh; K. Hashi; K. Aoki; T. Fukunaga

doi:10.1016/j.jnoncrysol.2007.05.066

Structural observation of amorphous (Ti_0.676Zr_0.324)D_0.31 by neutron and X-ray diffraction

K. Itoh, K. Hashi, K. Aoki, T. Fukunaga

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

Neutron and X-ray diffraction were used to elucidate the structure of amorphous (Ti_0.676Zr_0.324)D_0.31 prepared by mechanical milling under a deuterium gas atmosphere. Moreover, reverse Monte Carlo modeling was employed to obtain further insight into the location of the deuterium atoms. The results informed us that deuterium atoms are located in the tetrahedral sites formed by Ti and Zr. Additionally, it was found that about 93% of the deuterium atoms locate in the tetrahedral sites and about 40% occupy the holes of tetrahedral units consisting of 3Ti + 1Zr.

Original language	English
Pages (from-to)	3049-3052
Number of pages	4
Journal	Journal of Non-Crystalline Solids
Volume	353
Issue number	32-40
DOIs	https://doi.org/10.1016/j.jnoncrysol.2007.05.066
Publication status	Published - Oct 15 2007
Externally published	Yes

Keywords

Amorphous metals
Diffraction and scattering measurements
Glasses
Mechanical alloying
Metallic glasses
Modeling and simulation
Neutron diffraction/scattering
Short-range order
Structure
X-ray diffraction
X-rays

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Ceramics and Composites
Condensed Matter Physics
Materials Chemistry

Access to Document

10.1016/j.jnoncrysol.2007.05.066

Cite this

@article{30fd986132304e1b8c40a36290b548fe,

title = "Structural observation of amorphous (Ti0.676Zr0.324)D0.31 by neutron and X-ray diffraction",

abstract = "Neutron and X-ray diffraction were used to elucidate the structure of amorphous (Ti0.676Zr0.324)D0.31 prepared by mechanical milling under a deuterium gas atmosphere. Moreover, reverse Monte Carlo modeling was employed to obtain further insight into the location of the deuterium atoms. The results informed us that deuterium atoms are located in the tetrahedral sites formed by Ti and Zr. Additionally, it was found that about 93% of the deuterium atoms locate in the tetrahedral sites and about 40% occupy the holes of tetrahedral units consisting of 3Ti + 1Zr.",

keywords = "Amorphous metals, Diffraction and scattering measurements, Glasses, Mechanical alloying, Metallic glasses, Modeling and simulation, Neutron diffraction/scattering, Short-range order, Structure, X-ray diffraction, X-rays",

author = "K. Itoh and K. Hashi and K. Aoki and T. Fukunaga",

note = "Funding Information: This work was partially supported by the Ministry of Education, Science, Sports and Culture, Grant-in-Aid for Young Scientists (B) and Scientific Research in Priority Areas.",

year = "2007",

month = oct,

day = "15",

doi = "10.1016/j.jnoncrysol.2007.05.066",

language = "English",

volume = "353",

pages = "3049--3052",

journal = "Journal of Non-Crystalline Solids",

issn = "0022-3093",

publisher = "Elsevier",

number = "32-40",

}

TY - JOUR

T1 - Structural observation of amorphous (Ti0.676Zr0.324)D0.31 by neutron and X-ray diffraction

AU - Itoh, K.

AU - Hashi, K.

AU - Aoki, K.

AU - Fukunaga, T.

N1 - Funding Information: This work was partially supported by the Ministry of Education, Science, Sports and Culture, Grant-in-Aid for Young Scientists (B) and Scientific Research in Priority Areas.

PY - 2007/10/15

Y1 - 2007/10/15

N2 - Neutron and X-ray diffraction were used to elucidate the structure of amorphous (Ti0.676Zr0.324)D0.31 prepared by mechanical milling under a deuterium gas atmosphere. Moreover, reverse Monte Carlo modeling was employed to obtain further insight into the location of the deuterium atoms. The results informed us that deuterium atoms are located in the tetrahedral sites formed by Ti and Zr. Additionally, it was found that about 93% of the deuterium atoms locate in the tetrahedral sites and about 40% occupy the holes of tetrahedral units consisting of 3Ti + 1Zr.

AB - Neutron and X-ray diffraction were used to elucidate the structure of amorphous (Ti0.676Zr0.324)D0.31 prepared by mechanical milling under a deuterium gas atmosphere. Moreover, reverse Monte Carlo modeling was employed to obtain further insight into the location of the deuterium atoms. The results informed us that deuterium atoms are located in the tetrahedral sites formed by Ti and Zr. Additionally, it was found that about 93% of the deuterium atoms locate in the tetrahedral sites and about 40% occupy the holes of tetrahedral units consisting of 3Ti + 1Zr.

KW - Amorphous metals

KW - Diffraction and scattering measurements

KW - Glasses

KW - Mechanical alloying

KW - Metallic glasses

KW - Modeling and simulation

KW - Neutron diffraction/scattering

KW - Short-range order

KW - Structure

KW - X-ray diffraction

KW - X-rays

UR - http://www.scopus.com/inward/record.url?scp=34548546809&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=34548546809&partnerID=8YFLogxK

U2 - 10.1016/j.jnoncrysol.2007.05.066

DO - 10.1016/j.jnoncrysol.2007.05.066

M3 - Article

AN - SCOPUS:34548546809

SN - 0022-3093

VL - 353

SP - 3049

EP - 3052

JO - Journal of Non-Crystalline Solids

JF - Journal of Non-Crystalline Solids

IS - 32-40

ER -