Structural study of neutral-ionic transition in DMTTF-CA

Y. Nogami; M. Taoda; K. Oshima; S. Aoki; T. Nakayama; A. Miura

doi:10.1016/0379-6779(94)02826-K

Structural study of neutral-ionic transition in DMTTF-CA

Y. Nogami, M. Taoda, K. Oshima, S. Aoki, T. Nakayama, A. Miura

Research output: Contribution to journal › Article › peer-review

11 Citations (Scopus)

Abstract

Dimethyltetrathiafulvalene-p-chloranil (DMTTF-CA), showing a particular neutral(N)-ionic(I) transition from a N phase into a NI coexisting phase by cooling, was structural analyzed by X-ray at 29K, 48K, 109K and 293K. Below Tc of 65K, changes observed in unit cell parameters, bond lengths and anisotropic temperature factors indicate 1) a increase in degree of charge transfer(CT) from a DMTTF donor to a CA acceptor and 2) a formation of a molecular dimerization, in I part of the coexisting phase. A possible staging superlattice was not observed.

Original language	English
Pages (from-to)	1219-1220
Number of pages	2
Journal	Synthetic Metals
Volume	70
Issue number	1-3
DOIs	https://doi.org/10.1016/0379-6779(94)02826-K
Publication status	Published - Mar 15 1995

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Condensed Matter Physics
Mechanics of Materials
Mechanical Engineering
Metals and Alloys
Materials Chemistry

Access to Document

10.1016/0379-6779(94)02826-K

Cite this

@article{f1e3a727c78a40be8e237aaaf5758b25,

title = "Structural study of neutral-ionic transition in DMTTF-CA",

abstract = "Dimethyltetrathiafulvalene-p-chloranil (DMTTF-CA), showing a particular neutral(N)-ionic(I) transition from a N phase into a NI coexisting phase by cooling, was structural analyzed by X-ray at 29K, 48K, 109K and 293K. Below Tc of 65K, changes observed in unit cell parameters, bond lengths and anisotropic temperature factors indicate 1) a increase in degree of charge transfer(CT) from a DMTTF donor to a CA acceptor and 2) a formation of a molecular dimerization, in I part of the coexisting phase. A possible staging superlattice was not observed.",

author = "Y. Nogami and M. Taoda and K. Oshima and S. Aoki and T. Nakayama and A. Miura",

year = "1995",

month = mar,

day = "15",

doi = "10.1016/0379-6779(94)02826-K",

language = "English",

volume = "70",

pages = "1219--1220",

journal = "Synthetic Metals",

issn = "0379-6779",

publisher = "Elsevier BV",

number = "1-3",

}

TY - JOUR

T1 - Structural study of neutral-ionic transition in DMTTF-CA

AU - Nogami, Y.

AU - Taoda, M.

AU - Oshima, K.

AU - Aoki, S.

AU - Nakayama, T.

AU - Miura, A.

PY - 1995/3/15

Y1 - 1995/3/15

N2 - Dimethyltetrathiafulvalene-p-chloranil (DMTTF-CA), showing a particular neutral(N)-ionic(I) transition from a N phase into a NI coexisting phase by cooling, was structural analyzed by X-ray at 29K, 48K, 109K and 293K. Below Tc of 65K, changes observed in unit cell parameters, bond lengths and anisotropic temperature factors indicate 1) a increase in degree of charge transfer(CT) from a DMTTF donor to a CA acceptor and 2) a formation of a molecular dimerization, in I part of the coexisting phase. A possible staging superlattice was not observed.

AB - Dimethyltetrathiafulvalene-p-chloranil (DMTTF-CA), showing a particular neutral(N)-ionic(I) transition from a N phase into a NI coexisting phase by cooling, was structural analyzed by X-ray at 29K, 48K, 109K and 293K. Below Tc of 65K, changes observed in unit cell parameters, bond lengths and anisotropic temperature factors indicate 1) a increase in degree of charge transfer(CT) from a DMTTF donor to a CA acceptor and 2) a formation of a molecular dimerization, in I part of the coexisting phase. A possible staging superlattice was not observed.

UR - http://www.scopus.com/inward/record.url?scp=0029274442&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0029274442&partnerID=8YFLogxK

U2 - 10.1016/0379-6779(94)02826-K

DO - 10.1016/0379-6779(94)02826-K

M3 - Article

AN - SCOPUS:0029274442

SN - 0379-6779

VL - 70

SP - 1219

EP - 1220

JO - Synthetic Metals

JF - Synthetic Metals

IS - 1-3

ER -

Structural study of neutral-ionic transition in DMTTF-CA

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this