Structure and catalysis of layered rock-salt type oxides for methane oxidation

T. Miyazaki; T. Doi; M. Kato; T. Miyake; I. Matsuura

doi:10.1016/S0169-4332(97)00347-4

Structure and catalysis of layered rock-salt type oxides for methane oxidation

T. Miyazaki, T. Doi, M. Kato, T. Miyake, I. Matsuura

Research output: Contribution to journal › Article › peer-review

12 Citations (Scopus)

Abstract

A comparison of X-ray photoemission spectra of LiFeO ₂ , LiCoO ₂ , and Li _x Ni _2-x O ₂ for the range of 0 < x ≤ 1 have been measured. A main O 1s XPS peak of LiNiO ₂ and LiCoO ₂ with a hexagonal type was observed at 531.9 eV, while that of LiInO ₂ , LiFeO ₂ with a tetragonal type and Li _x Ni _2-x O ₂ (x < 0.6) with a cubic type were about 531.4 eV. It was inferred from these results that the layered superstructure of LiNiO ₂ and LiCoO ₂ largely affected the formation of the active oxygen species for the high selective coupling reaction of methane.

Original language	English
Pages (from-to)	492-495
Number of pages	4
Journal	Applied Surface Science
Volume	121-122
DOIs	https://doi.org/10.1016/S0169-4332(97)00347-4
Publication status	Published - Nov 1997
Externally published	Yes

Keywords

C selectivity
Coupling oxidation
Layered structure
Methane
Rock-salt type
XPS

ASJC Scopus subject areas

Chemistry(all)
Condensed Matter Physics
Physics and Astronomy(all)
Surfaces and Interfaces
Surfaces, Coatings and Films

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10.1016/S0169-4332(97)00347-4

Cite this

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title = "Structure and catalysis of layered rock-salt type oxides for methane oxidation",

abstract = " A comparison of X-ray photoemission spectra of LiFeO 2 , LiCoO 2 , and Li x Ni 2-x O 2 for the range of 0 < x ≤ 1 have been measured. A main O 1s XPS peak of LiNiO 2 and LiCoO 2 with a hexagonal type was observed at 531.9 eV, while that of LiInO 2 , LiFeO 2 with a tetragonal type and Li x Ni 2-x O 2 (x < 0.6) with a cubic type were about 531.4 eV. It was inferred from these results that the layered superstructure of LiNiO 2 and LiCoO 2 largely affected the formation of the active oxygen species for the high selective coupling reaction of methane.",

keywords = "C selectivity, Coupling oxidation, Layered structure, Methane, Rock-salt type, XPS",

author = "T. Miyazaki and T. Doi and M. Kato and T. Miyake and I. Matsuura",

year = "1997",

month = nov,

doi = "10.1016/S0169-4332(97)00347-4",

language = "English",

volume = "121-122",

pages = "492--495",

journal = "Applied Surface Science",

issn = "0169-4332",

publisher = "Elsevier",

}

TY - JOUR

T1 - Structure and catalysis of layered rock-salt type oxides for methane oxidation

AU - Miyazaki, T.

AU - Doi, T.

AU - Kato, M.

AU - Miyake, T.

AU - Matsuura, I.

PY - 1997/11

Y1 - 1997/11

N2 - A comparison of X-ray photoemission spectra of LiFeO 2 , LiCoO 2 , and Li x Ni 2-x O 2 for the range of 0 < x ≤ 1 have been measured. A main O 1s XPS peak of LiNiO 2 and LiCoO 2 with a hexagonal type was observed at 531.9 eV, while that of LiInO 2 , LiFeO 2 with a tetragonal type and Li x Ni 2-x O 2 (x < 0.6) with a cubic type were about 531.4 eV. It was inferred from these results that the layered superstructure of LiNiO 2 and LiCoO 2 largely affected the formation of the active oxygen species for the high selective coupling reaction of methane.

AB - A comparison of X-ray photoemission spectra of LiFeO 2 , LiCoO 2 , and Li x Ni 2-x O 2 for the range of 0 < x ≤ 1 have been measured. A main O 1s XPS peak of LiNiO 2 and LiCoO 2 with a hexagonal type was observed at 531.9 eV, while that of LiInO 2 , LiFeO 2 with a tetragonal type and Li x Ni 2-x O 2 (x < 0.6) with a cubic type were about 531.4 eV. It was inferred from these results that the layered superstructure of LiNiO 2 and LiCoO 2 largely affected the formation of the active oxygen species for the high selective coupling reaction of methane.

KW - C selectivity

KW - Coupling oxidation

KW - Layered structure

KW - Methane

KW - Rock-salt type

KW - XPS

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U2 - 10.1016/S0169-4332(97)00347-4

DO - 10.1016/S0169-4332(97)00347-4

M3 - Article

AN - SCOPUS:0031549838

SN - 0169-4332

VL - 121-122

SP - 492

EP - 495

JO - Applied Surface Science

JF - Applied Surface Science

ER -

Structure and catalysis of layered rock-salt type oxides for methane oxidation

Abstract

Keywords

ASJC Scopus subject areas

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