Structure and properties of (BEDSe-TTF)(Fn-TCNQ) charge transfer complexes (n = 1, 2, 4)

T. Mochida; H. Moriyama; T. Hasegawa; R. Kondo; S. Kagoshima; Y. Iwasa

doi:10.1016/S0379-6779(98)00578-5

Structure and properties of (BEDSe-TTF)(Fn-TCNQ) charge transfer complexes (n = 1, 2, 4)

T. Mochida, H. Moriyama, T. Hasegawa, R. Kondo, S. Kagoshima, Y. Iwasa

Research output: Contribution to journal › Conference article › peer-review

9 Citations (Scopus)

Abstract

Charge transfer complexes of bis(ethylenediselena)-tetrathiafulvalene (BEDSe-TTF) with a variety of Fn-TCNQ (n = 1, 2, 4, including isomers) are synthesized. In this family, only F₁-TCNQ afforded a conducting complex. Other acceptors gave mixed stack insulators, which undergo antiferromagnetic phase transitions. 2,5-F₂- and 2,3-F₂-TCNQ also yielded a polymorph with a novel type of crystal structure, showing a double-chain donor arrangement.

Original language	English
Pages (from-to)	1678-1679
Number of pages	2
Journal	Synthetic Metals
Volume	102
Issue number	1-3
DOIs	https://doi.org/10.1016/S0379-6779(98)00578-5
Publication status	Published - Jun 1999
Externally published	Yes
Event	Proceedings of the 1998 International Conference on Science and Technology of Synthetic Metals (ICSM-98) - Montpellier Duration: Jul 12 1998 → Jul 18 1998

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Condensed Matter Physics
Mechanics of Materials
Mechanical Engineering
Metals and Alloys
Materials Chemistry

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10.1016/S0379-6779(98)00578-5

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title = "Structure and properties of (BEDSe-TTF)(Fn-TCNQ) charge transfer complexes (n = 1, 2, 4)",

abstract = "Charge transfer complexes of bis(ethylenediselena)-tetrathiafulvalene (BEDSe-TTF) with a variety of Fn-TCNQ (n = 1, 2, 4, including isomers) are synthesized. In this family, only F1-TCNQ afforded a conducting complex. Other acceptors gave mixed stack insulators, which undergo antiferromagnetic phase transitions. 2,5-F2- and 2,3-F2-TCNQ also yielded a polymorph with a novel type of crystal structure, showing a double-chain donor arrangement.",

author = "T. Mochida and H. Moriyama and T. Hasegawa and R. Kondo and S. Kagoshima and Y. Iwasa",

note = "Funding Information: * Corresponding author. E-mail: mochida@toho-u.ac.jp This work was partly supported by the Grant-in-aid from the Ministry of Education, Science, Sports and Culture, Japan.; Proceedings of the 1998 International Conference on Science and Technology of Synthetic Metals (ICSM-98) ; Conference date: 12-07-1998 Through 18-07-1998",

year = "1999",

month = jun,

doi = "10.1016/S0379-6779(98)00578-5",

language = "English",

volume = "102",

pages = "1678--1679",

journal = "Synthetic Metals",

issn = "0379-6779",

publisher = "Elsevier BV",

number = "1-3",

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TY - JOUR

T1 - Structure and properties of (BEDSe-TTF)(Fn-TCNQ) charge transfer complexes (n = 1, 2, 4)

AU - Mochida, T.

AU - Moriyama, H.

AU - Hasegawa, T.

AU - Kondo, R.

AU - Kagoshima, S.

AU - Iwasa, Y.

N1 - Funding Information: * Corresponding author. E-mail: mochida@toho-u.ac.jp This work was partly supported by the Grant-in-aid from the Ministry of Education, Science, Sports and Culture, Japan.

PY - 1999/6

Y1 - 1999/6

N2 - Charge transfer complexes of bis(ethylenediselena)-tetrathiafulvalene (BEDSe-TTF) with a variety of Fn-TCNQ (n = 1, 2, 4, including isomers) are synthesized. In this family, only F1-TCNQ afforded a conducting complex. Other acceptors gave mixed stack insulators, which undergo antiferromagnetic phase transitions. 2,5-F2- and 2,3-F2-TCNQ also yielded a polymorph with a novel type of crystal structure, showing a double-chain donor arrangement.

AB - Charge transfer complexes of bis(ethylenediselena)-tetrathiafulvalene (BEDSe-TTF) with a variety of Fn-TCNQ (n = 1, 2, 4, including isomers) are synthesized. In this family, only F1-TCNQ afforded a conducting complex. Other acceptors gave mixed stack insulators, which undergo antiferromagnetic phase transitions. 2,5-F2- and 2,3-F2-TCNQ also yielded a polymorph with a novel type of crystal structure, showing a double-chain donor arrangement.

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U2 - 10.1016/S0379-6779(98)00578-5

DO - 10.1016/S0379-6779(98)00578-5

M3 - Conference article

AN - SCOPUS:0033137637

SN - 0379-6779

VL - 102

SP - 1678

EP - 1679

JO - Synthetic Metals

JF - Synthetic Metals

IS - 1-3

T2 - Proceedings of the 1998 International Conference on Science and Technology of Synthetic Metals (ICSM-98)

Y2 - 12 July 1998 through 18 July 1998

ER -

Structure and properties of (BEDSe-TTF)(Fn-TCNQ) charge transfer complexes (n = 1, 2, 4)

Abstract

ASJC Scopus subject areas

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