113Cd MAS and Static NMR Study of Chlorocadmate Glasses

Shinichi Sakida; Hironobu Nakata; Yoji Kawamoto

doi:10.1246/cl.2003.786

¹¹³Cd MAS and Static NMR Study of Chlorocadmate Glasses

Shinichi Sakida, Hironobu Nakata, Yoji Kawamoto

Environmental Management Center

Research output: Contribution to journal › Article › peer-review

Abstract

¹¹³Cd magic-angle spinning (MAS) and static NMR spectra were measured of fourteen kinds of chlorocadmate glasses to reveal the chlorine coordination environments around Cd²⁺ in the glasses in detail. The spectra of the glasses suggest that the glass structures are mainly composed of infinite double-chains of edge-shared CdCl₆ octahedra, being independent of the CdCl₂ content and the kinds of chlorides except for CdCl₂. ¹¹³Cd MAS and static NMR spectroscopies enabled us to reveal not only chlorine coordination number of Cd but also linkage manners between CdCl₆ octahedra in the glasses.

Original language	English
Pages (from-to)	786-787
Number of pages	2
Journal	Chemistry Letters
Volume	32
Issue number	9
DOIs	https://doi.org/10.1246/cl.2003.786
Publication status	Published - Sept 5 2003

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Chemistry(all)

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abstract = "113Cd magic-angle spinning (MAS) and static NMR spectra were measured of fourteen kinds of chlorocadmate glasses to reveal the chlorine coordination environments around Cd2+ in the glasses in detail. The spectra of the glasses suggest that the glass structures are mainly composed of infinite double-chains of edge-shared CdCl6 octahedra, being independent of the CdCl2 content and the kinds of chlorides except for CdCl2. 113Cd MAS and static NMR spectroscopies enabled us to reveal not only chlorine coordination number of Cd but also linkage manners between CdCl6 octahedra in the glasses.",

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N2 - 113Cd magic-angle spinning (MAS) and static NMR spectra were measured of fourteen kinds of chlorocadmate glasses to reveal the chlorine coordination environments around Cd2+ in the glasses in detail. The spectra of the glasses suggest that the glass structures are mainly composed of infinite double-chains of edge-shared CdCl6 octahedra, being independent of the CdCl2 content and the kinds of chlorides except for CdCl2. 113Cd MAS and static NMR spectroscopies enabled us to reveal not only chlorine coordination number of Cd but also linkage manners between CdCl6 octahedra in the glasses.

AB - 113Cd magic-angle spinning (MAS) and static NMR spectra were measured of fourteen kinds of chlorocadmate glasses to reveal the chlorine coordination environments around Cd2+ in the glasses in detail. The spectra of the glasses suggest that the glass structures are mainly composed of infinite double-chains of edge-shared CdCl6 octahedra, being independent of the CdCl2 content and the kinds of chlorides except for CdCl2. 113Cd MAS and static NMR spectroscopies enabled us to reveal not only chlorine coordination number of Cd but also linkage manners between CdCl6 octahedra in the glasses.

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¹¹³Cd MAS and Static NMR Study of Chlorocadmate Glasses

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