TY - JOUR
T1 - Synthesis and crystal structure of a [70] fullerene-pentacene monoadduct
AU - Shirai, Hitoshi
AU - Tajima, Tomoyuki
AU - Kubo, Kentaro
AU - Nishihama, Takuya
AU - Miyake, Hideaki
AU - Takaguchi, Yutaka
N1 - Publisher Copyright:
© 2016 The Chemical Society of Japan.
PY - 2016
Y1 - 2016
N2 - We succeeded in the first isolation of a single pure regioisomer of a C70-acene monoadduct. 1,9-Diels-Alder monoadducts of C70 with pentacene derivatives were obtained by not only the Diels-Alder reaction but also a one-pot reaction using stable dihydropentacene derivatives, 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ), and C70. The X-ray crystallographic study of a single pure regioisomer 2b confirmed positions of the linkage between C70 and acenes for the first time, and revealed unique columnar stacks.
AB - We succeeded in the first isolation of a single pure regioisomer of a C70-acene monoadduct. 1,9-Diels-Alder monoadducts of C70 with pentacene derivatives were obtained by not only the Diels-Alder reaction but also a one-pot reaction using stable dihydropentacene derivatives, 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ), and C70. The X-ray crystallographic study of a single pure regioisomer 2b confirmed positions of the linkage between C70 and acenes for the first time, and revealed unique columnar stacks.
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U2 - 10.1246/bcsj.20150378
DO - 10.1246/bcsj.20150378
M3 - Article
AN - SCOPUS:84963860986
SN - 0009-2673
VL - 89
SP - 437
EP - 443
JO - Bulletin of the Chemical Society of Japan
JF - Bulletin of the Chemical Society of Japan
IS - 4
ER -