Synthesis and oxidative polymerization of dialkyl fluorene-9,9-dicarboxylates

Yanying Zhang; Song Tu; Koichi Mitsudo; Hideo Tanaka; Shunzo Suematsu; Kenji Machida; Daisuke Horii; Shuichi Ishimoto; Kenji Tamamitsu

doi:10.1016/j.tetlet.2009.08.052

Synthesis and oxidative polymerization of dialkyl fluorene-9,9-dicarboxylates

Yanying Zhang, Song Tu, Koichi Mitsudo, Hideo Tanaka, Shunzo Suematsu, Kenji Machida, Daisuke Horii, Shuichi Ishimoto, Kenji Tamamitsu

School of Engineering

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

Novel long-chain dialkyl fluorene-9,9-dicarboxylates were synthesized by treating fluorene with lithium diisopropylamide followed by alkyl chloroformates. The fluorene derivatives were readily electro-oxidized to form electroactive films on the surface of a glassy carbon electrode. From the viewpoint of suitable potential window (from -2.5 to 1.5 V vs Ag/Ag⁺), cyclic voltammograms of the films indicated the electroactive properties of the fluorene derivatives that make them good candidates for electrochemical capacitor materials.

Original language	English
Pages (from-to)	6057-6059
Number of pages	3
Journal	Tetrahedron Letters
Volume	50
Issue number	44
DOIs	https://doi.org/10.1016/j.tetlet.2009.08.052
Publication status	Published - Nov 4 2009

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/j.tetlet.2009.08.052

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title = "Synthesis and oxidative polymerization of dialkyl fluorene-9,9-dicarboxylates",

abstract = "Novel long-chain dialkyl fluorene-9,9-dicarboxylates were synthesized by treating fluorene with lithium diisopropylamide followed by alkyl chloroformates. The fluorene derivatives were readily electro-oxidized to form electroactive films on the surface of a glassy carbon electrode. From the viewpoint of suitable potential window (from -2.5 to 1.5 V vs Ag/Ag+), cyclic voltammograms of the films indicated the electroactive properties of the fluorene derivatives that make them good candidates for electrochemical capacitor materials.",

author = "Yanying Zhang and Song Tu and Koichi Mitsudo and Hideo Tanaka and Shunzo Suematsu and Kenji Machida and Daisuke Horii and Shuichi Ishimoto and Kenji Tamamitsu",

note = "Funding Information: This work was partially supported by Industrial Technology Research Grant program in 2005 from New Energy and Industrial Technology Development Organization (NEDO) in Japan. We also thank the SC-NMR Laboratory of Okayama University for 1 H and 13 C NMR analyses. ",

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T1 - Synthesis and oxidative polymerization of dialkyl fluorene-9,9-dicarboxylates

AU - Zhang, Yanying

AU - Tu, Song

AU - Mitsudo, Koichi

AU - Tanaka, Hideo

AU - Suematsu, Shunzo

AU - Machida, Kenji

AU - Horii, Daisuke

AU - Ishimoto, Shuichi

AU - Tamamitsu, Kenji

N1 - Funding Information: This work was partially supported by Industrial Technology Research Grant program in 2005 from New Energy and Industrial Technology Development Organization (NEDO) in Japan. We also thank the SC-NMR Laboratory of Okayama University for 1 H and 13 C NMR analyses.

PY - 2009/11/4

Y1 - 2009/11/4

N2 - Novel long-chain dialkyl fluorene-9,9-dicarboxylates were synthesized by treating fluorene with lithium diisopropylamide followed by alkyl chloroformates. The fluorene derivatives were readily electro-oxidized to form electroactive films on the surface of a glassy carbon electrode. From the viewpoint of suitable potential window (from -2.5 to 1.5 V vs Ag/Ag+), cyclic voltammograms of the films indicated the electroactive properties of the fluorene derivatives that make them good candidates for electrochemical capacitor materials.

AB - Novel long-chain dialkyl fluorene-9,9-dicarboxylates were synthesized by treating fluorene with lithium diisopropylamide followed by alkyl chloroformates. The fluorene derivatives were readily electro-oxidized to form electroactive films on the surface of a glassy carbon electrode. From the viewpoint of suitable potential window (from -2.5 to 1.5 V vs Ag/Ag+), cyclic voltammograms of the films indicated the electroactive properties of the fluorene derivatives that make them good candidates for electrochemical capacitor materials.

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Synthesis and oxidative polymerization of dialkyl fluorene-9,9-dicarboxylates

Abstract

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