Abstract
Functionalizations of the boranato group of phosphine-boranes have been investigated. Trimethylphosphine-borane readily reacted with methanesulfonic acid in dichloromethane with evolution of hydrogen. The resulting trimethylphosphine-methylsulfonyloxyborane was subjected to nucleophilic substitution reaction on the boron atom with arenethiols or secondary phosphine-boranes in the presence of NaH. The reactivities of the substitution products obtained were also investigated. A new phosphine-borane having a P-B-P-B-P-BP-B bond linkage was synthesized.
| Original language | English |
|---|---|
| Pages (from-to) | 2846-2849 |
| Number of pages | 4 |
| Journal | Bulletin of the Chemical Society of Japan |
| Volume | 63 |
| Issue number | 10 |
| DOIs | |
| Publication status | Published - 1990 |
| Externally published | Yes |
ASJC Scopus subject areas
- Chemistry(all)